Studies on Biologically Active Coordiation Compounds of Metal Ions(Ⅶ)——Synthesize, Character, Antituberculin and Toxicity of Rare Earth Para-Amino-Salicylates

Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (8): 759.

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Studies on Biologically Active Coordiation Compounds of Metal Ions(Ⅶ)——Synthesize, Character, Antituberculin and Toxicity of Rare Earth Para-Amino-Salicylates

Chen Shuying, Zhang Xinhua, Wang Jingyu, Yu Cuangming, Jiang Yuan, Zhang Xunkai

Vepartment of Chemistry, Lanzhou University, Lanzhou

Received:1987-02-05 Online:1988-08-24 Published:1988-08-24

Abstract

Abstract: Fourteen new rare earth para-aminosalicylates were synthesized and characterized by elemenial analysis, IR, UV, Molar conductance, TG-DTA, and X-ray powder diffraction, Their chemical formulae were proved to be RE(PAS)₃nH₂Owhere REare earth elements except Sc, Pm, Gd, PAS. para-aminosalicylate, n=1~3. The infrared spectra showed that rare earth elements are chelated by carboxyl group and hydroxyl group. Antituberculin and toxicity research showed rare earth para-aminosalicylates are less toxicity and alittle more efficient than sodium para-aminosalicylate in the inhibition of tuberculin.

Key words: Rare earth coordiation compound, Para-amino-salicylates, Synthesis, Charaeter

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Chen Shuying, Zhang Xinhua, Wang Jingyu, Yu Cuangming, Jiang Yuan, Zhang Xunkai . Studies on Biologically Active Coordiation Compounds of Metal Ions(Ⅶ)——Synthesize, Character, Antituberculin and Toxicity of Rare Earth Para-Amino-Salicylates[J]. Chem. J. Chinese Universities, 1988, 9(8): 759.

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Studies on Biologically Active Coordiation Compounds of Metal Ions(Ⅶ)——Synthesize, Character, Antituberculin and Toxicity of Rare Earth Para-Amino-Salicylates

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