Preparation of Ti3C2-MXene/CuS/PVDF Composite Photothermal Membrane and Its Solar-driven Interfacial Water Evaporation Performance

doi:10.7503/cjcu20240469

Abstract

Abstract:

Ti₃C₂-MXene/CuS composite was synthesized by chemical etching and solvothermal method， and then Ti₃C₂-MXene/CuS/PVDF（polyvinylidene fluoride） composite photothermal film was obtained by vacuum filtration. Finally， its interfacial water evaporation performance was studied. X-ray diffraction and scanning electron microscopy characterization showed that CuS nanoparticles successfully coated Ti₃C₂-MXene and filled its lamellar gap. The results of interfacial water evaporation revealed that the best performance was obtained at the reaction temperature of 180 ℃ and the reaction time of 9 h. The interfacial evaporation rate and evaporation efficiency were 1.92 kg·m^‒2·h^‒1 and 110.4%， respectively under light intensity of 1 kW/m². In addition， desalination effect and cycling stability in seawater desalination of the composite photothermal film is good. The results of UV-Vis diffuse reflectance spectroscopy（DRS） and photothermal conversion performance showed that the combination of Ti₃C₂-MXene and CuS improved the light absorption capacity and photothermal conversion efficiency. By exerting the synergistic effect between them， the photothermal conversion and interfacial evaporation properties of the materials were significantly improved. This work can provide reference for the development of low cost and high performance photothermal conversion materials.

Key words: Interfacial water evaporation, Photothermal conversion, Ti₃C₂-MXene, CuS

CLC Number:

TB34

TrendMD:

JIANG Yanli, XU Yunsong, WANG Jiankang, LI Weihao, SONG Ying, WANG Xinzhi, YAO Zhongping. Preparation of Ti₃C₂-MXene/CuS/PVDF Composite Photothermal Membrane and Its Solar-driven Interfacial Water Evaporation Performance[J]. Chem. J. Chinese Universities, 2025, 46(4): 20240469.

Figures/Tables 20

References 28

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Reaction temperature/℃	Absorption rate（%）			Total（%）
Reaction temperature/℃	UV region	Vis region	NIR region	Total（%）
120	94.78	96.25	94.87	95.55
150	95.47	96.53	95.01	95.80
180	96.03	96.60	95.59	96.42

Reaction temperature/℃	Absorption rate（%）			Total（%）
Reaction temperature/℃	UV region	Vis region	NIR region	Total（%）
120	94.78	96.25	94.87	95.55
150	95.47	96.53	95.01	95.80
180	96.03	96.60	95.59	96.42

Reaction time/h	Absorption rate（%）			Total（%）
Reaction time/h	UV region	Vis region	NIR region	Total（%）
9	96.14	96.99	95.78	96.42
12	96.03	96.60	95.59	96.13
15	94.88	96.20	94.59	95.53

Reaction time/h	Absorption rate（%）			Total（%）
Reaction time/h	UV region	Vis region	NIR region	Total（%）
9	96.14	96.99	95.78	96.42
12	96.03	96.60	95.59	96.13
15	94.88	96.20	94.59	95.53

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Preparation of Ti₃C₂-MXene/CuS/PVDF Composite Photothermal Membrane and Its Solar-driven Interfacial Water Evaporation Performance

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