Syntheses of MIL-53 MOFs Materials and Their Catalytic Properties in Strecker Reactions

doi:10.7503/cjcu20190201

Abstract

Abstract: Four metal organic frameworks(MOFs), NH₂-MIL-53(Sc), NH₂-MIL-53(Al), MIL-53(Sc) and NO₂-MIL-53(Sc), were synthesized via changing the metal center and functional group of ligand, hereafter, their catalytic performance in the formation of α-aminonitrile(donated Strecker reaction) was investigated. Noteworthy, it is shown that the reusable NH₂-MIL-53(Sc) shows very good catalytic performance for Strecker reaction. Hereafter, comparing the catalytic experiments between NH₂-MIL-53(Sc) and NH₂-MIL-53(Al), the influence of metal ion radius and unsaturated coordination metal sites on Strecker reaction were analyzed. Furthermore, in comparison with the catalytic effects between NH₂-MIL-53(Sc) and MIL-53(Sc), the results demonstrated that the amino group can be served as the Lewis base sites, which can promote Strecker reaction through Lewis acid and Lewis base bifunctional synergistic mechanism. In addition, comparing the catalytic performances between NO₂-MIL-53(Sc) and MIL-53(Sc), it is confirmed that the NO₂ group on the catalyst structure has an important influence on the Strecker reaction. Finally, in comparison with the catalytic effects among NH₂-MIL-53(Sc), scandium nitrate and 2-aminoterephthalic acid(ATA) ligand, it is concluded that the nanoscale pore structure of NH₂-MIL-53(Sc) is the key factor to improve the selectivity of product in Strecker reaction.

Key words: Metal organic frameworks, MIL-53, Lewis acid and Lewis base bifunctional catalysis, Porous structure, Strecker reaction

CLC Number:

TrendMD:

WANG Pengcheng, SHAN Liang, FAN Yong, WANG Li, XU Jianing, WU Shujie. Syntheses of MIL-53 MOFs Materials and Their Catalytic Properties in Strecker Reactions[J]. Chem. J. Chinese Universities, 2019, 40(8): 1655.

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