Adsorption Behavior of Metal-organic Framework NH2-MIL-53(Al) for Diclofenac Sodium in Aqueous Solution†

doi:10.7503/cjcu20170378

Abstract

Abstract:

The metal-organic framework(MOF) material of NH₂-MIL-53(Al) was solvothermally synthesized, and characterized by powder X-ray diffraction(PXRD), scanning electron microscopy(SEM) and Fourier transform infrared spectroscopy(FTIR). The adsorption behavior of the as-prepared NH₂-MIL-53(Al) for diclofenac sodium(DCF) was studied in aqueous solution. The experimental results showed that NH₂-MIL-53(Al) had a high adsorption capacity on the target material and reach adsorption equilibrium in 40 min when the concentration of DCF was 5 mg/L. Furthermore, the adsorption kinetics of NH₂-MIL-53(Al) for DCF conformed to the pseudo second-order kinetics model. Langmuir model and Freundlich model were used to fit the adsorption isotherms, and the Langmuir model showed a better fit. The experiment of cyclic adsorption showed that NH₂-MIL-53(Al) had a good recycle performance. Moreover, the possible adsorption mechanism was demonstrated by the combination of ζ potential tests and adsorption effect experiments under different pH values.

Key words: NH2-MIL-53(Al), Diclofenac sodium, Adsorption capacity, Adsorption mechanism

CLC Number:

O611

TrendMD:

WANG Xiaobing, SHI Xiuyi, ZHOU Xingjun, QIU Xiuzhen, LU Wenguan. Adsorption Behavior of Metal-organic Framework NH₂-MIL-53(Al) for Diclofenac Sodium in Aqueous Solution^†[J]. Chem. J. Chinese Universities, 2018, 39(2): 206.

Figures/Tables 9

Fig.1 Molecular structure of DCF

Fig.2 Simulated(a) and experimental(b) PXRD patterns(A), SEM image(B) and FTIR spectrum(C) of NH2-MIL-53(Al)

Fig.3 Time profile of DCF adsorption on NH2-MIL-53(Al)(A, B), pseudo-first-order kinetics model(C) and pseudo-second-order kinetics model(D)

Table 1 Kinetic parameters for adsorption of DCF on NH2-MIL-53(Al)

Pseudo-first-order model			Pseudo-second-order kinetics model
R²	q_e/(mg·g^-1)	k₁/min^-1	R²	q_e/(mg·g^-1)	k₂/(g·mg^-1·min^-1)
0.9664	7.360	0.098	0.9985	9.662	0.0221

Fig.4 Adsorption isotherm of DCF on NH2-MIL-53(Al) a. Langmuir isotherm; b. Freundlich isotherm.

Table 2 Parameters of adsorption isotherm derived from the Langmuir and Freundlich models

Langmuir model			Freundlich model
q_max/(mg·g^-1)	b/(L·mg^-1)	R²	K	n	R²
71.3	0.1006	0.962	16.910	3.462	0.933

Fig.5 Reusability of NH2-MIL-53(Al) toward adsorption of DCF

Fig.6 Effects of pH on DCF adsorption(A) and ζ potential of NH2-MIL-53(Al)(B)

Fig.7 Plausible mechanism of DCF adsorption on NH2-MIL-53(Al) at pH<4(A) and 4<pH<7(B)

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Adsorption Behavior of Metal-organic Framework NH₂-MIL-53(Al) for Diclofenac Sodium in Aqueous Solution^†

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