Freeze-drying Synthesis and Characterization of Li2FeSiO4/C Cathode Materials for Lithium Ion Batteries

doi:10.7503/cjcu20160925

Chem. J. Chinese Universities ›› 2017, Vol. 38 ›› Issue (8): 1436.doi: 10.7503/cjcu20160925

• Physical Chemistry • Previous Articles Next Articles

Freeze-drying Synthesis and Characterization of Li₂FeSiO₄/C Cathode Materials for Lithium Ion Batteries

ZHANG Dong¹, LI Haoming¹, QIU Hailong¹, CHEN Gang¹, YUE Huijuan², LIU Anhua^2,3

1. Key Laboratory of Physics and Technology for Advanced Batteries, Ministry of Education, College of Physics, Jilin University, Changchun 130012, China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;
3. Key Laboratory of High Performance Ceramic Fibers of Ministry of Education, College of Materials, Xiamen University, Xiamen 361005, China

Received:2016-12-22 Revised:2017-07-17 Online:2017-08-10 Published:2017-07-17
Supported by:
Supported by the Science and Technology Development Planning of Jilin Province, China(No.20150204030GX), the Natural Science Foundation of Jilin Province, China(No.20160101320JC) and the Open Fund of Key Laboratory of High Performance Ceramic Fibers, Ministry of Education, Xiamen University, China(No.201602).

Abstract

Abstract:

Li₂FeSiO₄/C nanocomposites were prepared by freeze-dying synthesis. X-ray diffraction, Raman spectrometry, field emission scanning electron microscopy and N₂ adsorption-desorption were used to investigate the effect of dry method on the physical characteristics of Li₂FeSiO₄/C. The results show that Li₂FeSiO₄ obtained by freeze-drying method(DG) exhibits smaller particle size and larger specific surface area. The electrochemical performance was studied by galvanostatic charge-discharge and electrochemical impedance spectra. Compared to the Li₂FeSiO₄ obtained by ordinary drying method(HG), DG exhibits better rate capability, and the discharge capacity of 106.7 mA·h/g can be achieved at 2C rate.

Key words: Lithium ion battery, Cathode material, Li₂FeSiO₄, Freeze-drying, Lithium ion battery, Cathode material, Li₂FeSiO₄, Freeze-drying

CLC Number:

TrendMD:

ZHANG Dong, LI Haoming, QIU Hailong, CHEN Gang, YUE Huijuan, LIU Anhua. Freeze-drying Synthesis and Characterization of Li₂FeSiO₄/C Cathode Materials for Lithium Ion Batteries[J]. Chem. J. Chinese Universities, 2017, 38(8): 1436.

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Freeze-drying Synthesis and Characterization of Li₂FeSiO₄/C Cathode Materials for Lithium Ion Batteries

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