Preparation and Lithium Storage Performance of Nanostructured V2O5 with 0/1/2 Dimensional Hybrid Morphologies

doi:10.7503/cjcu20160839

Abstract

Abstract:

Orthorhombic V₂O₅ nanomaterial with 0/1/2 dimensional hybrid morphologies(H-V₂O₅) was prepared by sol-gel method combined with freeze-drying technique using P123 as structure-directing agent. The microstructure and morphology of the prepared samples were analyzed by X-ray diffraction(XRD) and Scanning electron microscopy(SEM), and the lithium sto-rage performance was characterized by cyclic voltammetry(CV), constant current charge/discharge, and electrochemical impedance spectroscopy(EIS) tests. The results showed that H-V₂O₅ possessed high lithium sto-rage capacity, excellent cycling stability, and outstan-ding high rate capability. When cycled at a constant current density of 1 A/g, the H-V₂O₅ delivered a stable discharge capacity of 117.5 mA·h/g after 500 cycles, corresponding to capacity retention of 94.4%; even at a very high current density of 5 A/g, the H-V₂O₅ still showed a discharge capacity of 88.2 mA·h/g, which is much superior than that for two dimensional sheet-like V₂O₅ nanomaterial prepared without the assistance of P123.

Key words: Lithium-ion battery, Cathode material, V₂O₅, Nanomaterial, Lithium storage performance

CLC Number:

O646

TrendMD:

XIE Zhiping, YAO Jinhuan, LIU Canzheng, JIANG Jiqiong, LI Yanwei. Preparation and Lithium Storage Performance of Nanostructured V₂O₅ with 0/1/2 Dimensional Hybrid Morphologies[J]. Chem. J. Chinese Universities, 2017, 38(8): 1442.

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Preparation and Lithium Storage Performance of Nanostructured V₂O₅ with 0/1/2 Dimensional Hybrid Morphologies

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