In situ Solvothermal Synthesis, Structure and Luminescent Properties of a Compound with Copper(Ⅰ) Halides Chain†

doi:10.7503/cjcu20160757

Abstract

Abstract:

A new compound formulated (C₁₀H₂₂N₂)₃[Cu₉I₁₄Br](C₁₀H₂₂N₂=N,N'-diethyl-1,4-diazabicyclo-[2.2.2]octane) was synthesized under solvothermal condition via in situ copper reduction and characterized by single crystal X-ray diffraction(XRD), elemental analysis, powder X-ray diffraction(PXRD) and Infrared spectroscopy. (C₁₀H₂₂N₂)₃[Cu₉I₁₄Br] crystallizes in monoclinic crystal system, space group C2/c with a=2.6233(5) nm, b=1.6299(3) nm, c=1.6707(3) nm, β=117.31(3)°, V=6.347(2) nm³. The title compound is constructed by organic cationic templates and anionic copper(Ⅰ) halide chains. The organic templates in this structure originated from the in situ N-alkylation reaction between N,N'-dimethyl-1,4-diazabicyclo[2.2.2]octane and alcohol solution. At ambient temperature, the title compound showed excellent luminescent property.

Key words: Copper halide, Copper halides chain, In situ reaction, Crystal structure, Luminescent property

TrendMD:

XIN Bingjing, LI Peng, LUO Lisha, XIA Tian, LI Guanghua. In situ Solvothermal Synthesis, Structure and Luminescent Properties of a Compound with Copper(Ⅰ) Halides Chain^†[J]. Chem. J. Chinese Universities, 2017, 38(4): 530.

Figures/Tables 5

Fig.1 ORTEP drawing of the asymmetric unit(A), the copper halide chain structure(B) and 3D packing motif of compound(C10H22N2)3[Cu9I14Br](C)

Fig.2 X-ray powder diffraction patterns of compound (C10H22N2)3[Cu9I14Br] a. Simulated; b. experimental.

Fig.3 XPS spectra of compound (C10H22N2)3[Cu9I14Br] (A) Cu2p; (B) I3d; (C) Br3d.

Fig.4 Mechanism of in situ alkylation reaction in the synthesis of compound (C10H22N2)3[Cu9I14Br]

Fig.5 Excitation(a) and emission(b) spectra of compound (C10H22N2)3[Cu9I14Br] in the solid state at room temperature

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