Fabrication of Superhydrophobic Film of Co(OH)2CO3 Nanowires and Its Anticorrosion†

doi:10.7503/cjcu20160633

Abstract

Abstract:

Superhydrophobic film of Co(OH)₂CO₃ nanowires was fabricated on nickel foils by hydrothermal method. The film exhibits superhydrophobicity after being modified by dodecanthiol(DDT), water contact angle and water gliding angle on the surface is 152.3° and 5°, respectively. The results reveal that the synergistic effects of hierarchical structures with micro/nanometer scale combining with low surface energy material induced the formation of superhydrophobicity. Compared with pristine nickel foil and unmodified Co(OH)₂CO₃ nanowires film, the film modified with DDT performs preferable properties of anticorrosion. The researches are expected to provide a reference for the fabrication of superhydrophobic metal surface and investigations of its properties of anticorrosion.

Key words: Nickel foil, Superhydrophobicity, Nanowires, Hydrothermal method, Anti-corrosion

TrendMD:

SHI Yanlong, FENG Xiaojuan, WANG Suiqian, FENG Chunchun. Fabrication of Superhydrophobic Film of Co(OH)₂CO₃ Nanowires and Its Anticorrosion^†[J]. Chem. J. Chinese Universities, 2017, 38(3): 456.

Figures/Tables 9

Fig.1 SEM images of pristine nickel foil(A) and superhydrophobic nickel constructed by combining hydrothermal and surface modification(B, C)

Fig.2 Images of water droplet on pristine nickel(A), pristine nickel modified by DDT(B), superhydrophobic nickel treated by hydrothermal and DDT modification(C, D)

Fig.3 XPS spectra of Co(OH)2CO3 film on nickel substrate before(a) and after(b) DDT modification(A) and the characteristic peak of S2p of DDT modified Co(OH)2CO3 film(B)

Fig.4 Schematic diagram of fabrication and formation mechanism of superhydrophobic nickel

Fig.5 Relationship of water contact angles and friction times of superhydrophobic nickel The inset is a simulation device for the friction measurement.

Fig.6 Relationship of contact angles of superhydrophobic nickel with immersion time(A) and pH value(B) (A) In 3.5% NaCl aqueous solution;(B) in acidic and basic solution.

Fig.7 Potentiodynamic polarization curves of pristine nickel(a), Co(OH)2CO3 film without modification(b) and Co(OH)2CO3treated by DDT modification(c)

Table 1 Electrochemical parameters correspond to Fig.7

Sample	B_a/(mV·dec^-1)	B_c/(mV·dec^-1)	10⁵ I_corr/(A·cm^-2)	E_corr /V(vs. SCE)	Corrosion rate(%)
a	7.116	8.806	1.26	-0.517
b	6.442	10.260	0.158	-0.220	87.46
c	3.350	6.638	0.0091	-0.165	99.27

Fig.8 Electrochemical impedance spectroscopy of the pristine nickel(a), Co(OH)2CO3 film without modification(b) and Co(OH)2CO3treated by DDT modification(c)

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Fabrication of Superhydrophobic Film of Co(OH)₂CO₃ Nanowires and Its Anticorrosion^†

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