Controllable Synthesis and Performance of Micro-nano Structure MFe2O4(M=Zn, Co) in Lithium-ion Batteries†

doi:10.7503/cjcu20140728

Abstract

Abstract:

Micro-nano structure MFe₂O₄(M=Zn, Co) materials were synthesized directly by hydrothermal method. The structural and morphological properties of the samples were investigated by means of X-ray diffraction(XRD) and transmission electron microscopy(TEM). The electrochemical performance of MFe₂O₄(M=Zn, Co) was examined by galvanostatic charge-discharge test and electrochemical alternate current(AC) impedance technique. The results show that hollow sphere CoFe₂O₄ and ZnFe₂O₄ have a reversible capacity of 1180 and 655 mA·h/g after 50 cycles, which are higher than those of solid sphere materials. At the same time, the formation mechanism of different morphology was studied.

Key words: Micro-nano structure, Hydrothermal synthesis, Anode material, Lithium-ion battery

CLC Number:

O646

TrendMD:

YUE Hongyun, WANG Qiuxian, ZHANG Xue, HUA Shuang, MA Hua, YUE Dongyuan, YANG Shuting. Controllable Synthesis and Performance of Micro-nano Structure MFe₂O₄(M=Zn, Co) in Lithium-ion Batteries^†[J]. Chem. J. Chinese Universities, 2015, 36(4): 745.

Figures/Tables 8

Fig.1 XRD patterns of the materials HZ, SZ(A) and HC, SC(B) (A) a. JCPDS No.22-1012; b. SZ; c. HZ. (B) a. JCPDS No.03-0864; b. SC; c. HC.

Table 1 XRD parameters and grain sizes of the samples

Sample	(hkl)	2θ/(°)	FWHM	Grain size/nm	Crystalline interplanar spacing of (311)/nm
HZ	(311)	35.328	0.379	20.77	0.2538
SZ	(311)	35.403	0.498	16.56	0.2533
JCPDS No.22-1012	(311)	35.264			0.2543
HC	(311)	35.562	0.580	14.22	0.2522
SC	(311)	35.250	0.655	12.58	0.2543
JCPDS No.03-0864	(311)	35.451			0.2530

Fig.2 TEM images(A, B, D, E) and SAED patterns(C, F) of HZ(A—C) and SZ(D—F)

Fig.3 TEM images of the products synthesized at 200 ℃ for 1 h(A), 3 h(B), 6 h(C), 12 h(D) and 24 h(E)

Scheme 1 Schematic illustration of the formation procedures of hollow spheres

Fig.4 Cycling performance of HZ, SZ(A) and HC, SC(B) at a current density of 60 mA/g

Fig.5 Discharge(a—c)-charge(a'—c') profiles of HZ(A), SZ(B), HC(C) and SC(D) in the voltage range between 0.005—3.0 V at a current density of 60 mA/g a, a': The 1st cycle; b, b': the 2nd cycle; c, c': the 10th cycle.

Fig.6 AC impedance spectra for HZ, SZ(A) and HC, SC(B) after 50 cycles

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Controllable Synthesis and Performance of Micro-nano Structure MFe₂O₄(M=Zn, Co) in Lithium-ion Batteries^†

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