Rhodamine Derivative ABDO/Er3+ Composite Fluorescent Probe in Response to Temperature†

doi:10.7503/cjcu20131096

Abstract

Abstract:

A rhodamine derivative(ABDO) based on rhodamine 6G and diethylene triamine was synthesized and used as a fluorescent probe to detect temperature. The fluorescence spectra and ultraviolet-visible absorbant spectra were used to study the variation trend of ABDO-Er complex with the temperature. The stabilization time of ABDO-Er complex in constant temperature bath and fluorescence intensity of ABDO-Er complex, ABDO and rhodamine 6G with different temperature were studied. The results showed that ABDO-Er complex was directly proportional to temperature. Therefore, ABDO-Er complex could be used to monitor the change of environmental temperature.

Key words: Temperature, ABDO-Er complex, Fluorescence probe

CLC Number:

O657.3

TrendMD:

XU Hui, DAI Yanna, SHAN Hongyan, FEI Qiang, HUAN Yanfu, LI Guanghua, FENG Guodong. Rhodamine Derivative ABDO/Er³⁺ Composite Fluorescent Probe in Response to Temperature^†[J]. Chem. J. Chinese Universities, 2014, 35(4): 736.

Figures/Tables 7

Scheme 1 Synthetic process of compound ABDO

Fig.1 Absorption spectra of 10 μmol/L ABDO(a) and ABDO-Er complex(10 μmol/L Er3+)(b)(A) and Job’s plot of 1:1 complex of receptor ABDO and Er3+(B) The total concentration of Er3+ and receptor ABDO was 50 μmol/L.

Fig.2 Fluorescence emission spectra of ABDO-Er(A) and proposed mechanism for the fluorescence enhancement of ABDO in the presence of Er3+(B) c(Er3+)/(μmol·L-1): a. 0; b. 1; c. 5; d. 10; e. 50; f. 100.

Fig.3 Fluorescence intensity of ABDO-Er(10 μmol/L) at 40 ℃(a), 50 ℃(b) and 60 ℃(c)

Fig.4 Fluorescence emission intensity of 10 μmol/L ABDO(a), 0.1 μmol/L rhodamine 6G(b) and 10 μmol/L ABDO-Er(c) at different temperatures(A) and 10 μmol/L ABDO fluorescence intensity vs. time after heating to 50 ℃(B)

Fig.5 Fluorescence emission intensities of 10 μmol/L ABDO(a) with 10 μmol/L(b), 30 μmol/L(c) and 100 μmol/L(d) Er3+ at different temperatures(A) and formation constants(K) for ABDO-Er complex at different temperatures(B)

Fig.6 UV-Vis absorption spectra of ABDO-Er(10 μmol/L) at different temperatures(A) and relative absorbance of ABDO-Er complex at different temperatures(B) Temperature/℃: a. 25; b. 30; c. 35; d. 40; e. 45; f. 50; g. 55; h. 60.

References 23

[1]	Hu Q.L., Study of Optical Fiber Temperature Measurement System Based on Fluorescence Mechanism, Yanshan University, Qinhuangdao, 2010, 1—7
	(胡俏丽. 基于荧光机理的光纤温度测量技术的研究, 秦皇岛: 燕山大学, 2010, 1—7)
[2]	Castrellon U. J., Optics and Lasers in Engineering, 2005, 43(6), 633—644
[3]	Wu J. L., Han D. K., Li C. P., Control & Automation,2008, 24, 1—9
	(武金玲, 韩登科, 李翠萍, 微计算机信息, 2008, 24, 1—9)
[4]	Zhang W. W., He X. D., Gao Y. Q., A Fluorescence Temperature Sensor Probe and Its Producing Method CP101701855A,2012-04-11
	(张巍巍, 何兴道, 高益庆. 一种荧光温度传感器探针及其制作方法, CP101701855A, 2012-04-11)
[5]	Murray A. M., Melton L. A., Appl. Opt., 1985, 24(17), 2783—2787
[6]	Schrum K. F., Williams A. M., Haerther S. A., Ben-Amotz D., Anal. Chem., 1994, 66(17), 2788—2790
[7]	Engeser M., Fabbrizzi L., Licchelli M., Sacchi D.,Chem. Commun., 1999, (13), 1191—1192
[8]	Chandrasekharan N., Kelly L. A., J. Am. Chem. Soc., 2001, 123, 9898—9899
[9]	Chapman C. F., Liu Y., Sonek G. J., Tromberg B. J., Photochemistry and Photobiology,1995, 62(3), 416—425
[10]	Zhang P.R., Sun L., Based on C Language C8051F Series Microcontroller Principle and Application, Tsinghua University Press, Beijing, 2007, 32—78
	(张培仁, 孙力. 基于C语言C8051F系列微控制器原理与应用. 北京: 清华大学出版社, 2007, 32—78)
[11]	Wang H. G., Wang S., Chem. J. Chinese Universities,1986, 7(9), 780—782
	(王怀公, 王苏. 高等学校化学学报, 1986, 7(9), 780—782)
[12]	Jin X.L., Wu X. L., Liang P., Lei L., Li J. L., Shi Z., The 6th National Conference on Chemical Biology, Xiamen, 2009, 242
	(金洗郎, 武祥龙, 梁攀, 雷磊, 李剑利, 史真, 第六届全国化学生物学学术会议论文集, 厦门, 2009, 242)
[13]	Khansari S., Duzyer S., Sinha-Ray S., Hockenberger A., Yarin A. L., Pourdeyhimi B., Mol. Pharmaceutics,2013, 10(12), 4509—4526
[14]	Micu I., Brideau C., Stys P. K., International Society for Optics and Photonics,2012, 8207, 82076C-1—82076C-8
[15]	Chan J., Dodani S. C., Chang C. J., Nature Chemistry,2012, 4, 973—984
[16]	Hu Z. Q., Lin C. S., Wang X. M., Ding L., Cui C. L., Liu S. F., Lu H. Y., Chem. Commun., 2010, 46(21), 3765—3767
[17]	Liu S. K., Zhou C. Y., Du J. H., Gao J. G., Zhou J., Chin. J. Anal. Chem., 2013, 41(5), 732—737
	(刘士坤, 周春燕, 杜建华, 高吉刚, 周杰. 分析化学, 2013, 41(5), 732—737)
[18]	Yuan Y. H., Feng F., Tian M. Z., Meng S. M., Bai Y. F., Chem. J. Chinese Universities,2011, 32(1), 62—66
	(袁跃华, 冯锋, 田茂忠, 孟双明, 白云峰. 高等学校化学学报, 2011, 32(1), 62—66)
[19]	Schäferling M., Angew. Chem. Int. Ed., 2012, 51(15), 3532—3554
[20]	Orellana G., Anal. Bioanal. Chem., 2004, 379(3), 344—346
[21]	Mao J., He Q., Liu W., Talanta,2010, 80(5), 2093—2098
[22]	Quang D. T., Wu J. S., Luyen N. D., Duong T., Dan N. D., Bao N. C., Quy P. T., Spectrochim Acta A,2011, 78(2), 753—756
[23]	Benesi H. A., Hildebrand J. H., J. Am. Chem. Soc., 1949, 71(8), 2703—2707

Rhodamine Derivative ABDO/Er³⁺ Composite Fluorescent Probe in Response to Temperature^†

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 23

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	QIU Xinsheng, WU Qin, SHI Daxin, ZHANG Yaoyuan, CHEN Kangcheng, LI Hansheng. Preparation and High Temperature Fuel Cell Performance of Ionic Crosslinked Sulfonated Polyimides for Proton Exchange Membranes [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220140.
[2]	GAO Jian, FENG Yiyu, FANG Wenyu, WANG Hui, GE Jing, FENG Wei. Alkane Grafted Phase Change Azobenzene Materials Based on Low Temperature Heat Release [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220146.
[3]	ZHANG Zhicai, WANG Yuge, GU Qianqian, LYU Yongpeng, XIAO Jianshu, YIN Yuan, SUN Hongguo, ZHENG Yafang, SUN Zhaoyan. Flocculation of Fillers in Isoprene Rubber and Its Effects on Properties [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220155.
[4]	JIAO Long, DAI Xuemin, MU Jianxin, DU Zhijun, WANG Hanfu, DONG Zhixin, QIU Xuepeng. Preparation and Properties of High Heat-resistant Polyimide Films for Flexible OLED [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220390.
[5]	LIU Kun, YIN Yuan, GENG Wenqiang, XIA Haotian, LI Hua. Influence Mechanism of Filling Transition Metal Oxide Catalyst with Different Components on Nitrogen Fixation in Dielectric Barrier Discharge [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220278.
[6]	TAN Lejian, ZHONG Xuanshu, WANG Jin, LIU Zongjian, ZHANG Aiying, YE Lin, FENG Zengguo. Low Critical Dissolution Temperature Behavior of β⁃Cyclodextrin and Its Application in the Preparation of β⁃Cyclodextrin Sheet Crystal with Ordered Nano⁃channel [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220405.
[7]	ZHANG Jie, YIN Bo, LIU Weixin, LIU Xingping, LIAN Wenxian, TANG Shaokun. Fabrication of Boehmite Fiber-reinforced Silica Aerogels and Their Performances [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220483.
[8]	QIAO Zhenghua, FAN Qi, HAO Jingcheng. Silicone Surfactant-enhanced Dual Networks and High Temperature Resistance Porous Silicone Elastomers [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220384.
[9]	ZHAO Baodong, LIU Yajing, PAN Yongfei, LIU Weixiao, GAO Fulei, WANG Yinglei. Synthesis and Properties of Energetic Plasticizer 2，2-Dinitropropyl Trifluoropropanoate [J]. Chem. J. Chinese Universities, 2021, 42(9): 2815.
[10]	HUANG Congcong, ZHANG Baoqing, LIU Chenyang. Predicting the Glass Transition Temperature of Polyimides： Group Additive Property Method and Assigning the Group Contributions to Unknown Groups [J]. Chem. J. Chinese Universities, 2021, 42(8): 2617.
[11]	CAO Kaiyue, PENG JinWu, LI Hongbin, SHI Chengying, WANG Peng, LIU Baijun. High-temperature Proton Exchange Membranes Based on Cross-linked Polybenzimidazole/hyperbranched-polymer Blends [J]. Chem. J. Chinese Universities, 2021, 42(6): 2049.
[12]	HAN Yixiu, WU Dianguo, LI Hongpu, YIN Hongyao, MEI Yongjun, FENG Yujun, ZHONG Zuqin. Interactions Between Hydrophobic Associating Poly（sodium acrylate） and a Zwitterionic Surfactant in Non-aqueous Media and Low Temperature Environment [J]. Chem. J. Chinese Universities, 2021, 42(6): 2056.
[13]	LI Xinyu, LI Zhiwei, ZHANG Xingyuan. Construction of Room Temperature Phosphorescence System of Thioflavin-based Polylactide/Benzenesulfonic Acid [J]. Chem. J. Chinese Universities, 2021, 42(6): 1987.
[14]	WU Tao, FANG Yuting, DONG Jie, ZHAO Xin, ZHANG Qinghua. Synthesis and Properties of Polyimide Resin Containing Acetylene and Benzoxazine Double Crosslinking Moieties [J]. Chem. J. Chinese Universities, 2021, 42(6): 1978.
[15]	SHI Ying, HU Guangjian, WU Minjie, LI Feng. Applications of Low Temperature Plasma for the Materials in Li-ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(5): 1315.