Synthesis of N,N-Dimethyl Pyridine Benzaldehyde-4-dimethylaminobenzoylhydrazone and Its Application for Selective Recognizing Cu2+

doi:10.7503/cjcu20130669

Abstract

Abstract:

A fluorescence chemosensor, N,N-dimethyl pyridine benzaldehyde-4-dimethylaminobenzoylhydrazone was synthesized and confirmed by means of ¹H NMR, ¹³C NMR and MS. The interactions between the metal ions and compound 1 were investigated via fluorescence spectrophotometry and UV-Vis spectroscopy. The results indicated that compound 1 showed a highly selective response to Cu²⁺. The addition of Cu²⁺ induced a dramatic enhancement in the fluorescence of compound 1 by 12.5 folds, whereas the other metal ions had little fluorescence quenching, for example Fe³⁺, Zn²⁺, Pb²⁺, Hg²⁺, Cd²⁺, Co²⁺, Ni²⁺, Li⁺, K⁺, Ca²⁺, Mg²⁺ and Ag⁺. Double reciprocal linear plot method showed that compound 1 coordinated with Cu²⁺ to form 1: 1 stable luminescent complex and the binding constants was ca. 2.0×10⁷ L/mol.

Key words: N,N-Dimethyl pyridine benzaldehyde-4-dimethylaminobenzoylhydrazone, Cu²⁺, Fluorescence enhancement

CLC Number:

O657
O614

TrendMD:

HAN Bing-Xing, WU Fang-Ying. Synthesis of N,N-Dimethyl Pyridine Benzaldehyde-4-dimethylaminobenzoylhydrazone and Its Application for Selective Recognizing Cu²⁺[J]. Chem. J. Chinese Universities, 2013, 34(11): 2483.

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Synthesis of N,N-Dimethyl Pyridine Benzaldehyde-4-dimethylaminobenzoylhydrazone and Its Application for Selective Recognizing Cu²⁺

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