Selective Detection of Pb2+ Using Poly(methylacrylic acid) Monolayer-protected Gold Nanoparticles

doi:10.7503/cjcu20130456

Abstract

Abstract:

In this work, the selective colorimetric detection of Pb²⁺ was studied using poly(methylacrylic acid) monolayer-protected gold nanoparticles(PMAA-@-GNPs). The GNPs with uniform size and distribution were firstly synthesized by the citrate reduction method. Then PMAA-@-GNPs were prepared by the strong binding of the GNPs and the thiol ends groups of the PMAA. The monolayer structure was proved by the dynamic light scattering, UV-visible spectra and transmission electron microscopy. In the presence of Pb²⁺, the color of the solution changed from wine red to purple and could be measured by visual inspection. TEM results demonstrated that the induced aggregation of GNPs by Pb²⁺ crosslinking carboxyl groups. The selectivity of Pb²⁺ detection has also been investigated by comparing the color changes of solutions with other metal ions, including Hg²⁺, Mg²⁺, Cu²⁺, Zn²⁺, Na⁺, Ni²⁺, Fe³⁺, Cd²⁺, K⁺ and Fe²⁺. After treated by EDTA, the aggregated PMMA-@-GNPs could be renewable and recycled detecting Pb²⁺.

Key words: Poly(methylacrylic acid), Gold nanoparticles, Pb²⁺, Detection

CLC Number:

O657
O631

TrendMD:

LI Jun-Bo, HAN Chen, ZHANG Shi-Jie, GUO Jin-Wu, ZHOU Hui-Yun. Selective Detection of Pb²⁺ Using Poly(methylacrylic acid) Monolayer-protected Gold Nanoparticles[J]. Chem. J. Chinese Universities, 2013, 34(10): 2303.

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Selective Detection of Pb²⁺ Using Poly(methylacrylic acid) Monolayer-protected Gold Nanoparticles

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