高等学校化学学报 ›› 2001, Vol. 22 ›› Issue (6): 1066.

• 综合评述 • 上一篇    下一篇

高分子胶束化的新途径及胶束的结构演化

刘世勇, 江明   

  1. 复旦大学高分子科学系和教育部聚合物分子工程重点实验, 上海 200433
  • 收稿日期:2000-06-22 出版日期:2001-06-24 发布日期:2001-06-24
  • 通讯作者: 江 明(1938年出生),男,教授,博士生导师,主要从事高分子物理化学研究.
  • 基金资助:

    国家自然科学基金(批准号:29992590;59773023);国家基础研究课题“高分子凝聚态基本问题研究”资助

New Approaches to Polymer Micellization and the Structural Evolution of the Micelles

LIU Shi-Yong, JIANG Ming   

  1. Department of Macromolecular Science and Key Laboratory of Molecular Engineering of Polymers of Educational Ministry, Fudan University, Shanghai 200433, China
  • Received:2000-06-22 Online:2001-06-24 Published:2001-06-24

摘要: 简述了嵌段共聚物和接枝共聚物在选择性溶剂中的胶束化行为.详细讨论了导致高分子胶束化的一些新途径,如利用特殊相互作用(氢键、离子相互作用和高分子/金属离子配位络合)、改变温度、介质环境和化学反应诱导等;并对高分子胶束结构的进一步演化以获得核交联和壳交联胶束作了简要的介绍.

关键词: 高分子, 胶束化, 新途径, 超分子自组装

Abstract: The classical micellization behavior of block or graft copolymers in selective solvent was briefle described and a variey of new approaches to polymer micellization caused by specific interactions(hydrogen bonding, ionic interaction, polymer-metal ion coordination interaction), change of termperature and media properties and chemical reactions, etc. was reviewed. Besides, new advances in the further evolution of the micelles leading to core cross linked micelles and shell cross linked micelles are discussed.

Key words: Polymer, Micellization, New approaches, Supramolecular self-assembly

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