高等学校化学学报 ›› 2004, Vol. 25 ›› Issue (12): 2381.

• 研究简报 • 上一篇    下一篇

用原子转移自由基方法合成新型大分子偶联剂

张洪文1, 艾鹏1, 姜彦1,2, 李宏途1, 张开1, 杨松茹1, 王静媛1   

  1. 1. 吉林大学化学学院, 长春130023;
    2. 齐齐哈尔大学生命科学学院, 齐齐哈尔161006
  • 收稿日期:2003-12-30 出版日期:2004-12-24 发布日期:2004-12-24

Synthesis of a Novel Macromolecular Coupling Agent from ATRP

ZHANG Hong-Wen1, AI Peng1, JIANG Yan1,2, LI Hong-Tu1, ZHANG Kai1, YANG Song-Ru1, WANG Jing-Yuan1   

  1. 1. College of Chemistry, Jilin University, Changchun 130023, China;
    2. College of Life Science, Qiqihaer University, Qiqihaer 161006, China
  • Received:2003-12-30 Online:2004-12-24 Published:2004-12-24

关键词: 原子转移自由基聚合, 大分子偶联剂, 阻尼性, 相容性

Abstract: A novel graft macromolecular coupling agent with well-defined structure was synthesized by atom transfer radical polymerization(ATRP). Since the silicon of graft polymers possesses a strong affinity to hydroxyl mineral, it gives fillers some new properties such as the increase of the interaction of fillers with matrix. The properties, structure of macromolecular coupling agent and its composite were studied by dynamic mechanical spectra, IR, UV, NMR, GPC and SEM.

Key words: Atom transfer radical polymerization(ATRP), Macromolecular coupling agent, Damping, Compatibility

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