高等学校化学学报
• 研究论文 • 上一篇
张瑶瑶,刘珊珊
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ZHANG Yaoyao，LIU Shanshan
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摘要： 将生物质衍生多元醇选择性转化为含氮化合物仍然是可持续化学领域的一项艰巨挑战. 虽然氢转移策略已成为传统还原胺化的一种环境友好型替代方法，但在多元醇转化过程中仍然存在难以精确调控C—C键选择性断裂的难题. 在此，我们报告了一种通过不同催化体系来调控多元醇选择性C—C键裂解从而生成不同含氮化合物.
关键词: 多元醇, 氢转移策略, N-杂环化合物
Abstract: The selective conversion of biomass-derived polyols to nitrogen-containing compounds remains a formidable challenge in sustainable chemistry. Although hydrogen transfer strategies have emerged as an environmentally friendly alternative to conventional reductive amination, the difficulty of precisely regulating the selective C—C bond breaking during polyol conversion remains. Herein, we report a method to regulate the selective C—C bond cleavage of polyols to produce different nitrogen compounds through different catalytic systems.
Key words: Polyols, Hydrogen transfer strategy, N-heterocyclic compounds
中图分类号:
O626
TrendMD:
张瑶瑶 刘珊珊. 催化剂调控的多元醇与2-硝基芳烃的选择性氢转移反应. 高等学校化学学报, doi: 10.7503/cjcu20250057.
ZHANG Yaoyao, LIU Shanshan. Catalyst-modulated selective hydrogen transfer reactions of polyols with 2-Nitroaromatics. Chem. J. Chinese Universities, doi: 10.7503/cjcu20250057.
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链接本文: http://www.cjcu.jlu.edu.cn/CN/10.7503/cjcu20250057
