超疏水碱式碳酸钴纳米线薄膜的制备及抗腐蚀性

doi:10.7503/cjcu20160633

高等学校化学学报 ›› 2017, Vol. 38 ›› Issue (3): 456.doi: 10.7503/cjcu20160633

超疏水碱式碳酸钴纳米线薄膜的制备及抗腐蚀性

石彦龙, 冯晓娟(), 王随乾, 冯春春

河西学院化学化工学院, 甘肃省河西走廊特色资源利用重点实验室, 张掖 734000

收稿日期:2016-09-12 出版日期:2017-03-10 发布日期:2017-02-22
作者简介:联系人简介: 冯晓娟, 女, 讲师, 主要从事新能源材料及功能材料方面的研究. E-mail:cherry-820@163.com
基金资助:
国家自然科学基金(批准号: 51263008)、甘肃省高等学校科研项目(批准号: 2016B-091)、甘肃省河西走廊特色资源利用重点实验室项目(批准号: XZ1407, XZ1603)、 2016年甘肃省省级大学生创新创业训练计划项目(批准号: 201610740004, 201610740003)和河西学院第六批大学生科技创新项目(批准号: 126, 001, 117)资助.

Fabrication of Superhydrophobic Film of Co(OH)₂CO₃ Nanowires and Its Anticorrosion^†

SHI Yanlong, FENG Xiaojuan^*(), WANG Suiqian, FENG Chunchun

College of Chemistry and Chemical Engineering, Key Laboratory of Hexi Corridor Resources Utilization of Gansu, Hexi University, Zhangye 734000, China

Received:2016-09-12 Online:2017-03-10 Published:2017-02-22
Contact: FENG Xiaojuan E-mail:cherry-820@163.com
Supported by:
† Supported by the National Natural Science Foundation of China(No. 20873101), the Scientific Research Foundation of the Higher Education Institutions of Gansu Province, China(No. 2016B-091), the General Program of the Key Laboratory of Hexi Corridor Resources Utilization of Gansu, China(Nos. XZ1603, XZ14007), 2016 Provincial Training Program of Innovation and Entrepreneurship for Undergraduates, China(Nos. 201610740004, 201610740003) and the Sixth Scientific Innovation for College Students of Hexi University, China(Nos. 126, 001, 117).

摘要/Abstract

摘要：

以镍为基底, 采用水热法在其表面制得碱式碳酸钴纳米线薄膜, 用十二烷基硫醇进行表面修饰后其表现出超疏水性, 水滴在其表面的接触角达到152.3°, 滚动角接近5°. 研究结果表明, 薄膜表面微纳米阶层结构及低表面物质的协同作用使其呈超疏水性. 与普通镍片和硫醇修饰前的碱式碳酸钴纳米线薄膜相比, 超疏水碱式碳酸钴纳米线薄膜具有更好的抗腐蚀性. 相关研究有望为超疏水金属表面的制备及其抗腐蚀性研究提供思路.

关键词: 镍片, 超疏水, 纳米线, 水热法, 抗腐蚀性

Abstract:

Superhydrophobic film of Co(OH)₂CO₃ nanowires was fabricated on nickel foils by hydrothermal method. The film exhibits superhydrophobicity after being modified by dodecanthiol(DDT), water contact angle and water gliding angle on the surface is 152.3° and 5°, respectively. The results reveal that the synergistic effects of hierarchical structures with micro/nanometer scale combining with low surface energy material induced the formation of superhydrophobicity. Compared with pristine nickel foil and unmodified Co(OH)₂CO₃ nanowires film, the film modified with DDT performs preferable properties of anticorrosion. The researches are expected to provide a reference for the fabrication of superhydrophobic metal surface and investigations of its properties of anticorrosion.

Key words: Nickel foil, Superhydrophobicity, Nanowires, Hydrothermal method, Anti-corrosion

TrendMD:

石彦龙, 冯晓娟, 王随乾, 冯春春. 超疏水碱式碳酸钴纳米线薄膜的制备及抗腐蚀性. 高等学校化学学报, 2017, 38(3): 456.

SHI Yanlong, FENG Xiaojuan, WANG Suiqian, FENG Chunchun. Fabrication of Superhydrophobic Film of Co(OH)₂CO₃ Nanowires and Its Anticorrosion^†. Chem. J. Chinese Universities, 2017, 38(3): 456.

图/表 9

Fig.1 SEM images of pristine nickel foil(A) and superhydrophobic nickel constructed by combining hydrothermal and surface modification(B, C)

Fig.2 Images of water droplet on pristine nickel(A), pristine nickel modified by DDT(B), superhydrophobic nickel treated by hydrothermal and DDT modification(C, D)

Fig.3 XPS spectra of Co(OH)2CO3 film on nickel substrate before(a) and after(b) DDT modification(A) and the characteristic peak of S2p of DDT modified Co(OH)2CO3 film(B)

Fig.4 Schematic diagram of fabrication and formation mechanism of superhydrophobic nickel

Fig.5 Relationship of water contact angles and friction times of superhydrophobic nickel The inset is a simulation device for the friction measurement.

Fig.6 Relationship of contact angles of superhydrophobic nickel with immersion time(A) and pH value(B) (A) In 3.5% NaCl aqueous solution;(B) in acidic and basic solution.

Fig.7 Potentiodynamic polarization curves of pristine nickel(a), Co(OH)2CO3 film without modification(b) and Co(OH)2CO3treated by DDT modification(c)

Table 1 Electrochemical parameters correspond to Fig.7

Sample	B_a/(mV·dec^-1)	B_c/(mV·dec^-1)	10⁵ I_corr/(A·cm^-2)	E_corr /V(vs. SCE)	Corrosion rate(%)
a	7.116	8.806	1.26	-0.517
b	6.442	10.260	0.158	-0.220	87.46
c	3.350	6.638	0.0091	-0.165	99.27

Fig.8 Electrochemical impedance spectroscopy of the pristine nickel(a), Co(OH)2CO3 film without modification(b) and Co(OH)2CO3treated by DDT modification(c)

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超疏水碱式碳酸钴纳米线薄膜的制备及抗腐蚀性

Fabrication of Superhydrophobic Film of Co(OH)₂CO₃ Nanowires and Its Anticorrosion^†

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超疏水碱式碳酸钴纳米线薄膜的制备及抗腐蚀性

Fabrication of Superhydrophobic Film of Co(OH)2CO3 Nanowires and Its Anticorrosion†

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Fabrication of Superhydrophobic Film of Co(OH)₂CO₃ Nanowires and Its Anticorrosion^†