高等学校化学学报

高等学校化学学报 ›› 2006, Vol. 27 ›› Issue (1): 9.

• 研究论文 • 上一篇    下一篇


不同孔径的介孔碳分子筛对VB12的吸附性质研究

郭卓, 朱广山, 辛明红, 高波, 裘式纶   

  1. 吉林大学无机合成与制备化学国家重点实验室, 长春 130012
  • 收稿日期:2005-01-05 出版日期:2006-01-10 发布日期:2006-01-10
  • 通讯作者: 裘式纶(1948年出生), 男, 博士, 教授, 博士生导师, 主要从事无机材料的合成. E-mail: sqiu@mail.jlu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号: 20101004)资助

Adsorption Behavior of VB12 on Mesoporous Carbon Molecular Sieves
with Different Pore Diameters

GUO Zhuo, ZHU Guang-Shan, XIN Ming-Hong, GAO Bo, QIU Shi-Lun   

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China
  • Received:2005-01-05 Online:2006-01-10 Published:2006-01-10
  • Contact: QIU Shi-Lun, E-mail: sqiu@mail.jlu.edu.cn

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摘要：

摘要利用SBA-15为模板, 在不同温度下合成了孔径大小在3.7(CMK-3-100)和6-3 nm(CMK-3-150)之间的介孔碳， 以其作为吸附剂, 研究了它们在水溶液中对VB12的吸附作用. 结果表明, CMK-3-130与CMK-3-100和CMK-3-150相比， 表现出对VB12最大的吸附能力(吸附能力为412.5 mg/g), 这是因为它有比较高的有序结构和比较大的孔容.

关键词: SBA-15; 介孔碳;  吸附性质;  VB12

Abstract:

AbstractThe CMK-3-130 exhibits the largest adsorption capacity than CMK-3-100 and CMK-3-150. Mesoporous carbon sieves were prepared from SBA-15 materials at different temperatures. This allows the synthesis of mesoporous carbons sieves with pore dismeters in the range from 3.7 nm(CMK-3-100) to 6.3 nm(CMK-3-150).The mesoporous carbons sieves were studied in the adsorption of VB12 from water solutions. The maximal adsorption capacity of 412.5 mg/g was found for CMK-3-130, which is probably a consequence of its highly ordered mesostructures and larger pore.

Key words: SBA-15; Mesoporous carbon; Adsorption behavior; VB12

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