高等学校化学学报

高等学校化学学报 ›› 2003, Vol. 24 ›› Issue (8): 1366.

• 研究简报 • 上一篇    下一篇

新型一维[Co(phen)(μ3-md)]n的水热合成与结构

李传碧, 张丽娟, 孙英华, 李泳, 王铁钢, 徐吉庆   

  1. 吉林大学化学学院, 无机合成与制备化学国家重点实验室, 长春 130023
  • 收稿日期:2002-05-30 出版日期:2003-08-24 发布日期:2003-08-24
  • 通讯作者: 徐吉庆(1937年出生),男,教授,博士生导师,从事功能簇合物材料及生物酶的化学模拟研究.E-mail:xjq@mail.jlu.edu.cn E-mail:xjq@mail.jlu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:29733090);高等学校博士学科点专项科研基金(批准号:1999018310)资助

Hydrothermal Synthesis and Structure of A Novel [Co(phen)(μ3-md)]n

LI Chuan-Bi, ZHANG Li-Juan, SUN Ying-Hua, LI Yong, WANG Tie-Gang, XU Ji-Qing    

  1. College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
  • Received:2002-05-30 Online:2003-08-24 Published:2003-08-24

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关键词: [Co(phen)(&mu, 3-md)]n, 晶体结构, 一维双链结构

Abstract: Anovel 1-Dcompound, [[Co(phen)(μ3-md)]n] n, was hydrothermally synthesized and characterized by single crystal X-ray diffraction analysis, elemental analysis and IRspectra.This compound was crystallized in monoclinic system, space group P2/C with a=0.8329(18) nm, b=1.04135(11) nm, c=1.8348(5) nm, β=100.436(18)°, Dc=1.706 mg/cm3, R1= 0.0379, wR2=0.0866. The 1-Ddouble-chain structure of the title compound is formed by benzene-1,3-dicarboxylate connected with three Co atoms.

Key words: [[Co(phen)(μ3-md)]n] n, Crystal structure, 1-D double-chain structure

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