高等学校化学学报

高等学校化学学报 ›› 2003, Vol. 24 ›› Issue (6): 980.

• 研究快报 • 上一篇    下一篇

三维无机-有机杂化骨架微孔化合物[Co3(BDC)3(EG)4]·2DMF的合成与结构

方千荣, 石鑫, 辛明红, 吴刚, 田歌, 朱广山, 李亚丰, 叶玲, 王春雷, 张震东, 唐璐璐, 裘式纶   

  1. 吉林大学化学学院, 无机合成与制备化学国家重点实验室, 长春 130023
  • 收稿日期:2002-12-02 出版日期:2003-06-24 发布日期:2003-06-24
  • 通讯作者: 裘式纶(1948年出生),男,博士,教授,博士生导师,从事无机固体材料化学研究.E-mail:sqiu@mail.jlu.edu.cn E-mail:sqiu@mail.jlu.edu.cn
  • 基金资助:

    国家重大基础研究计划“九七三”项目(批准号:G2000077507);国家自然科学基金(批准号:29873017和20101004)资助

Synthesis and Characteristic of 3-D Inorganic-organic Hybrid Framework Microporous Material [Co3(BDC)3(EG)4]·2DMF

FANG Qian-Rong, SHI Xin, XIN Ming-Hong, WU Gang, TIAN Ge, ZHU Guang-Shan, LI Ya-Feng, YE Ling, WANG Chun-Lei, ZHANG Zhen-Dong, TANG Lu-Lu, QIU Shi-Lun   

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, China
  • Received:2002-12-02 Online:2003-06-24 Published:2003-06-24

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关键词: 晶体结构, 无机-有机杂化骨架结构, 微孔材料

Abstract: A 3-D inorganic-organic hybrid framework microporous material [CO3(BDC)3(EG)4]·2DMF was synthesized under mild conditions and its crystal structure was determined bYUsing single crystal X-ray diffraction. The crystal structure was solved by a direct method and refined by full-matrix least-square method. The crystaLIs the triclinic system and belongs to space group P-1 with a=9.978(2) nm, b=11.223(2) nm, c=11.283(2) nm, α=102.26(3)°, β=113.52(3)°, γ=92.73(3)°, V=6.329(2) nm3, Z=1, Dc=1.565 Mg/m3, Mr=1 063.59, μ=1.183mm-1, F(000)=541, GOF=1.024, R=0.044 2, wR=0.124 9.

Key words: Crystal structure, Inorganic-organic hybrid framework, Microporous material

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