高等学校化学学报

高等学校化学学报 ›› 2002, Vol. 23 ›› Issue (11): 2040.

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新型无机-有机杂化微孔晶体Cd3(BDC)0.5(BTC)2(DMF)(H2O)·3DMF·H3O·H2O的合成与结构

石鑫, 方千荣, 辛明红, 吴刚, 田歌, 朱广山, 李亚丰, 王立锋, 王春雷, 商铁存, 裘式纶   

  1. 吉林大学化学学院, 无机合成与制备化学国家重点实验室, 长春130023
  • 收稿日期:2002-08-02 出版日期:2002-11-24 发布日期:2002-11-24
  • 通讯作者: 裘式纶(1948年出生),男,博士,教授,博士生导师,从事无机固体材料化学研究.E-mail:sqiu@mai.ljlu.edu.cn;朱广山(1971年出生),男,博士,教授,主要从事无机合成与制备化学研究.E-mail:zhugs@mai.ljlu.edu.cn E-mail:sqiu@mai.ljlu.edu.cn;zhugs@mai.ljlu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:29873017,20101004);国家重大基础研究“九七三”计划(批准号:G2000077507)资助

Synthesis and Structure of a Novel Inorganic-organic Hybrid Framework Microporous Material Cd3（BDC）0.5（BTC）2（DMF）（H2O）·3DMF·H3O·H2O

SHI Xin, FANG Qian-Rong, XIN Ming-Hong, WU Gang, TIAN Ge, ZHU Guang-Shan, LI Ya-Feng, WANG Li-Feng, WANG Chun-Lei, SHANG Tie-Cun, QIU Shi-Lun   

  1. College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
  • Received:2002-08-02 Online:2002-11-24 Published:2002-11-24

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关键词: 无机-有机杂化骨架, 微孔材料, 晶体结构

Abstract: A new inorganic-organic hybrid framework microporous material Cd3(BDC)0.5(BTC)2·(DMF)(H2O)·3DMF·H3O·H2O, in which two kinds of carboxylate ligands coordinate with cadmium ions synchronously, was obtained under a mild synthesis condition. The titled compound is crystallized in a monoclinic system, space group P2(1)/c with a=1.584 7(7) nm, b=1.426 7(6) nm, c=1.936 3(6) nm, β=113.186(7)°, V=4.024 6(3) nm3, Z=4, D X=1.947 mg/m3, M r=1 179.92, μ=1.662 mm-1, F(000)=2 344, R=0.074 8, wR=0.215 1. Three cadmium centers link with each other through BDC or BTC ligand to form a 3-D open framework.

Key words: Inorganic-organic hybrid frameworks, Microporous material, Crystal structure

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