高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (9): 1343.

• 研究快报 • 上一篇    下一篇

新型超分子化合物C6H20N2O64P2Mo18·8H2O的晶体结构及电催化作用

刘景华, 辛明红, 王恩波, 彭军, 毕丽华   

  1. 东北师范大学化学系, 长春 130024
  • 收稿日期:1999-05-27 出版日期:1999-09-24 发布日期:1999-09-24
  • 通讯作者: 王恩波
  • 作者简介:刘景华,女,43岁,副教授,访问学者,现在吉林农业大学工作.
  • 基金资助:

    国家自然科学基金(批准号:29771006)资助课题

Thc Crystal Structure and Electrocatalysis of Supermolecular Compound C6H20N2O64P2Mo18·8H2O

LIU Jing-Hua, XIN Ming-Hong, WANG En-Bo, PENG Jun, BI Li-Hua   

  1. Department of Chenistry, Northeast Normal University, Changchun 130024, China
  • Received:1999-05-27 Online:1999-09-24 Published:1999-09-24

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关键词: 超分子化合物, 晶体结构, 电催化作用

Abstract: Anovel compound formulated [NH2(CH2)4CHNH2COOH]H6P2Mo18O62has been synthesized and its structure has been characterized, which is the first example of aminoacid-heteropolyacid species.Crystal system is orthorhombic, space group P21212, unit cell dimensions: α=1.5722(3) nm, b=2.1181 (4) nm, c=1.2383(3) nm, α=90.04(3)°, β=90.00 (2)°, γ= 89.99 (3)°, V= 4.1236(14) nm3, Z=2, D0=2.437×103kg/m3, R=0.0387.Experimental result shows that the title compound has electrocatalysis reactivity.

Key words: Supermolecular compound, Crystal structure, Eletrocatalysis

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