高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (7): 1011.

• 论文 •    下一篇

C60乙二胺衍生物铂配合物的合成及其催化硅氢化性能

陈远荫1, 方鹏飞1, 朱绫2, 盛蓉生2   

  1. 1. 武汉大学化学学院, 武汉, 430072;
    2. 武汉大学分析测试系, 武汉, 430072
  • 收稿日期:1997-07-28 出版日期:1998-07-24 发布日期:1998-07-24
  • 通讯作者: 陈远荫,男,61岁,教授.
  • 作者简介:陈远荫,男,61岁,教授.
  • 基金资助:

    国家自然科学基金(批准号:29573115)资助课题.

Synthesis of Fullerene Ethylenediamine Derivative Platinum Complex and Its Catalytic Behavior in the Hydrosilylation of Olefins

CHEN Yuan-Yin1, FANG Peng-Fei1, ZHU Ling2, SHENG Rong-Sheng2   

  1. 1. School of Chemistry, Wuhan University, Wuhan, 430072;
    2. Department of Analysis and Measurement, Wuhan University, Wuhan, 430072
  • Received:1997-07-28 Online:1998-07-24 Published:1998-07-24

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摘要： C60与乙二胺反应,再与氯亚铂酸钾配位,得到了一种以C60衍生物为基的Pt(Ⅱ)配合物,并研究了其在烯烃与三乙氧基硅烷的硅氢加成反应中的催化性能。结果表明,该配合物为硅氢加成反应的高效催化剂,并对苯乙烯有独特的催化性能,以近100%的区域选择性得到α-加成产物。

关键词: 富勒烯, 铂配合物, 硅氢加成催化剂, 区域选择性

Abstract: Fullerene derivative ethylenediamine platinum complex was prepared by reacting fullerene(C60) with ethylenediamine, potassium chloroplatinite sequentially. The complex exhibited high catalytic activities for the hydrosilylation of olefins with triethoxysilane, and nearly 100% regioselectivity for styrene α-adduct.

Key words: Fullerene, Platinum complex, Hydrosilylation catalyst, Regioselectivity

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