高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (6): 843.

• 论文 • 上一篇    下一篇

有机-无机自由基盐(DBTTF)6PMo12O40·2H2O的合成、性质和晶体结构

陈亚光1, 刘景福1, 林永华2, 邢燕2, 贾恒庆2   

  1. 1. 东北师范大学化学系, 长春, 130024;
    2. 中国科学院长春应用化学研究所, 长春, 130022
  • 收稿日期:1997-04-29 出版日期:1998-06-24 发布日期:1998-06-24
  • 通讯作者: 刘景福
  • 作者简介:陈亚光,女,41,博±,副教授.
  • 基金资助:

    国家自然科学基金

Synthesis, Properties and Crystal Structure of Organic-inorganic Radical Salt(DBTTF)6HPMo12 O40·2H2O

CHEN Ya-Guang1, LIU Jing-Fu1, LIN Yong-Hua2, XING Yan2, JIA Heng-Qing2   

  1. 1. Department of Chemistry, Northeast Normal University, Changchun, 130024;
    2. Changchun Institute of Applied Chemistry, Acadimia Sinica, Changchun, 130022
  • Received:1997-04-29 Online:1998-06-24 Published:1998-06-24

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摘要： 用电解法制备了有机-无机自由基盐(DBTTF)6PMo12O40·2H2O.用红外光谱、电子光谱和电子自旋共振谱进行了表征,测定了其磁化率、导电性和单晶的晶体结构,该晶体属三斜晶系,P1空间群,晶胞参数为a=1.3787(7)nm,b=1.4204(2)nm,c=1.5702(2)nm,α=104.570(8)°,β=103.41(2)°,γ=95.80(2)°,V=2.853(2)nm3,Z=1,Dc=2.142Mg·m-3,R=0.0727.

关键词: 有机-无机自由基盐, 钼磷杂多阴离子, 二苯基四硫富瓦烯, 晶体结构

Abstract: Organic inorganic radical salt(DBTTF)6PMo12O40 ·2H2O was synthesized by electrocrystallization and characterized by IR spectrum, electronic spectrum and ESR technology. Its magnetic property, conductivity and crystal structure were determined. The title compound crystallized in a triclinic system with P1 space group, a =1.3787(7), b =1.4204(2), c =1.5702(2) nm, α =104.57(1)°, β =103.41(2)°, γ =95.80(2)°, V =2.853(2) nm3, Z =1 and a final R =0.0727.

Key words: Organic inorganic radical salt, Molybdophosphateheteropoly anion, Dibenzotetrathiofulvalene, Crystal structure

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