高等学校化学学报 ›› 1997, Vol. 18 ›› Issue (7): 1185.

• 综合评述 • 上一篇    下一篇

过渡金属配合物催化剂及其分子设计构思的发展与相互作用

万惠霖, 袁友珠, 高景星, 张鸿斌, 蔡启瑞   

  1. 厦门大学化学系, 物理化学研究所, 固体表面物理化学国家重点实验室, 厦门 361005
  • 收稿日期:1997-02-14 出版日期:1997-07-24 发布日期:1997-07-24
  • 通讯作者: 万惠霖, 男, 58岁, 教授, 博士导师.
  • 作者简介:万惠霖, 男, 58岁, 教授, 博士导师.
  • 基金资助:

    国家自然科学基金;中国石油化工总公司联合资助

Evolution and Significance of Molecular Design Conception in the Development of Stereo-selective Transition-metal Complex Catalysts

WAN Hui-Lin, YUAN You-Zhu, GAO Jing-Xing, ZHANG Hong-Bin, ZHU Gui-Yun   

  1. Department of Chemistry, Institute of Physical Chemistry, State Key Laboratoryfor Physical Chemistry of the Solid Surface, Xiamen University, Xiamen 361005
  • Received:1997-02-14 Online:1997-07-24 Published:1997-07-24

摘要: 讨论了某些不对称合成和α-烯烃定向配位聚合及α-烯烃氢甲酰化的过渡金属配合物定向络合催化剂的发展与催化剂分子设计构思的发展及相互促进作用,并藉以说明过渡金属配合物定向络合催化剂的分子设计已具备向计算机辅助设计发展的科学基础.

关键词: 不对称合成, 定向配位聚合, 氢甲酰化, 催化剂分子设计

Abstract: The mutual promotion of the development of stereo-selective coordination cata-lysts involving transition-metal coordination compounds and the development of the concep-tion of molecular design of such catalysts was discussed, as illustrated by three typical typesof stereo-selective coordination catalysis, namely, asymmetric synthesis, stereo-selective co-ordination polymerization of α-olefins, and hydroformylation of α-olefins.With this discus-sion, it is shown that for the molecular design of certain types of stereo-selective coordina-tion catalysts, there has already been sound scientific basis for the development of computer-aided design (CAD).

Key words: Asymmetric synthesis, Stereo-selective coordination polymerization, Hydro-formylation, Catalyst molecule design

中图分类号: 

TrendMD: