高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (9): 1353.

• 研究快报 • 上一篇    下一篇

层状锑磷酸嵌接式卟啉锰制备与模拟细胞色素氧化催化研究

胡希明1, 皮宗新1, 梅治乾1, 古国榜1, 黄仲涛2   

  1. 1. 华南理工大学应用化学系, 广州, 510641;
    2. 华南理工大学化学工程系, 广州, 510641
  • 收稿日期:1996-04-09 出版日期:1996-09-24 发布日期:1996-09-24
  • 通讯作者: 胡希明,男,43岁,副教授.
  • 作者简介:胡希明,男,43岁,副教授.
  • 基金资助:

    国家教育委员会优秀青年教师研究基金

Preparation of Layered Phosphatoantimonic Acid-Intercalated Manganese Porphyrin and Catalytic Oxidation of Simmulated Cytochrome

HU Xi-Ming1, PI Zong-Xin1, MEI Zhi-Qian1, GU Guo-Bang1, HUANG Zhong-Tao2   

  1. 1. Department of Applied Chemistry, South China University of Technology, Guangzhou, 510641;
    2. Department of Chemical Engineering, South China University of Technology, Guangzhou, 510641
  • Received:1996-04-09 Online:1996-09-24 Published:1996-09-24

关键词: 卟啉锰, 层状锑磷酸, 嵌接, 催化性能

Abstract: Manganese tetraphenylporphyrin as a guest molecule was intercalated in situ into the layered host material phosphatoantimonic acid.The porphyrin immobilized in the layered structure exhibits a fairly catalytic capability for the epoxidation of cyclohexene and the oxidation of n-octane by hydrogen peroxide, due to the prevention of the formation of μ-dimers.

Key words: Mangnese porphyrin, Layered phosphatoantimonic acid, Intercalation, Catalytic behaviour

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