高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (5): 812.

• 研究简报 • 上一篇    下一篇

含内环化与不含内环化固化理论间的对应关系

黄旭日, 肖兴才, 李泽生, 孙家鍾, 唐敖庆   

  1. 吉林大学理论化学研究所, 长春 130023
  • 收稿日期:1995-05-05 出版日期:1996-05-24 发布日期:1996-05-24
  • 通讯作者: 黄旭日,男, 32岁,博士,副教授.
  • 作者简介:黄旭日,男, 32岁,博士,副教授.
  • 基金资助:

    国家自然科学基金;国家教委博士点基金;霍英东教育基金

Correspondence Rule Between the Curing Theories with Cyclization ann without Cyclization

HUANG Xu-Ri, XIAO Xing-Cai, LI Ze-Sheng, SUN Chia-Chung, TANG Au-Chin   

  1. Institute of Theoretical Chemistry, Jilin University, Changchun 130023
  • Received:1995-05-05 Online:1996-05-24 Published:1996-05-24

关键词: 内环化, 非线性缩聚反应, 数量分布函数, 高分子矩

Abstract: By means of the sol fraction of the Aa1…Aai…Bb1…Bbi-type polymerization in which the cyclization is involved, the equilibrium number fraction distribution is obtained by using Lagrange's expansion techniques.Furthermore, a correspondence rule between the curing theories with cyclization and without cyclization is proposed.Using this rule various results of the curing theory with cyclization can be obtained directly from the corresponding ones of the curing theory without cyclization.

Key words: Cyclization, Non-linear polymerization, Equilibrium number fraction distribution, Polymer moment

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