高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (4): 663.

• 研究简报 • 上一篇    

正十二烷醇与环氧乙烷的加成反应动力学研究──最佳反应时间的确定

张仁权, 张维冰, 李葵英, 王万兴   

  1. 齐齐哈尔轻工学院化工系, 齐齐哈尔 161006
  • 收稿日期:1995-07-18 出版日期:1996-04-24 发布日期:1996-04-24
  • 通讯作者: 张仁权,男,55岁,副教授.
  • 作者简介:张仁权,男,55岁,副教授.

A Study of Dynamics About the Addition Reaction of n-Dodecyl Alcohol and Ethylene Oxide──Determining the Optimum Reaction Time

ZHANG Ren-Quan, ZHANG Wei-Bing, LI Kui-Ying, WANG Wan-Xing   

  1. Department of Chemical Engineering, Light Industry Institute of Qiqihar, Qiqihar 161006
  • Received:1995-07-18 Online:1996-04-24 Published:1996-04-24

关键词: 正十二烷醇聚氧乙烯醚, 碱催化, 聚合度

Abstract: In accordence with the reaction mechanism that the reaction of n-dodecyl alcoholethylene oxide(EO)is catalyzed by the strong base,the optimum reaction time expression ofthe relatively highest product containing at the given polymer number of EOis obtained bythe Laplace transform.Our expression was compared with Weibull's and Flory's ones undercertain conditions,and the relationship between the optimum reaction time and the averagepolymer number of EOis discussed.As an example,the conclusion is also proved with theresult that lauryl alcohol reacts with EOunder different catalytic conditions.

Key words: Polyoxyethylene n-didecyl alcohol ether, Base catalyst, Degree of polymerizationto compare our expression

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