高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (11): 1790.

• 研究简报 • 上一篇    下一篇

非对称八烷氧基取代酞菁聚硅氧烷的合成及其单分子膜

穆劲, 夏强, 华玉晶, 周伟东, 肖童   

  1. 山东大学胶体与界面化学研究所, 济南, 250100
  • 收稿日期:1994-12-20 修回日期:1995-03-16 出版日期:1995-11-24 发布日期:1995-11-24
  • 通讯作者: 穆劲,男,32岁,副教授.
  • 作者简介:穆劲,男,32岁,副教授.
  • 基金资助:

    国家“863”计划青年基金

Synthesis of Non-symmetric Octaalkoxy-Substituted Phthalocyaninato-polysiloxane and Its Monomolecular Films

MU Jin, XIA Qiang, HUA Yu-Jing, ZHOU Wei-Dong, XIAO Tong   

  1. Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100
  • Received:1994-12-20 Revised:1995-03-16 Online:1995-11-24 Published:1995-11-24

关键词: 酞菁聚硅氧烷, LB膜, &pi, -A曲线

Abstract: Poly[(2,3-dimethoxy-9, 10, 16, 17,23,24-hexaoctoxyphthalocyaninato)siloxane] was synthesized.UV-Vis spectra indicate that the strong cofacial interaction occurs between Pc units in the same main chain and the molecular aggregates of the polymer are formed in the LB film, The surface pressure-area isotherm shows the existence of the sharp phase transitions during the compression of the film. The polymer can be deposited on solid substrates to form LB films.

Key words: Phthalocyaninatopolysiloxane, LB film, π-A isotherm

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