高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (3): 363.

• 研究简报 • 上一篇    下一篇

圆二色谱研究两个新的呋喃雅槛蓝型倍半萜的绝对构型

程东亮1, 高建军1, 牛金奎1, 田瑄2   

  1. 1. 兰州大学化学系, 兰州大学应用有机化学国家重点实验室, 兰州 730000;
    2. 兰州大学有机化学研究所
  • 收稿日期:1992-04-29 修回日期:1992-12-01 出版日期:1993-03-24 发布日期:1993-03-24
  • 通讯作者: 程东亮
  • 基金资助:

    国家自然科学基金

Studies on the Absolute Configurations of Two 10-hydroxy-9-oxo-Furoeremophilanes Using CD Spectra

CHENG Dong-Liang1, GAO Jian-Jun1, NIU Jin-Kui1, TIAN Xuan2   

  1. 1. Department of Chemistry, National Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000;
    2. Institute of Organic Chemistry, Lanzhou University
  • Received:1992-04-29 Revised:1992-12-01 Online:1993-03-24 Published:1993-03-24

关键词: 圆二色谱, 呋喃雅槛蓝型倍半萜, 绝对构型

Abstract: Because of the absence of hydrogen in position 10, it is difficult to determine the C-10 configurations of 9-oxo-furoeremophilanes using1H NMRspectra.By means of CDspectra, absolute configurations of two new furoeremophilanes were established.Some aspects about CDspectra of 10-hydroxy-9-oxo-furoeremophilanes were discussed.

Key words: CD spectrum, Furoeremophilane, Absolute configuration

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