高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (11): 1355.

• 研究简报 • 上一篇    下一篇

N-氧化吡啶-2-甲醛单缩1,2-丙二胺Schiff碱镍配合物的晶体结构

阎世平, 姜宗慧, 廖代正, 王耕霖, 王如骥, 王宏根, 姚心侃   

  1. 南开大学化学系, 中心实验室, 天津, 300071
  • 收稿日期:1991-11-30 修回日期:1992-03-30 出版日期:1992-11-24 发布日期:1992-11-24
  • 通讯作者: 阎世平
  • 基金资助:

    国家自然科学基金

Crystal Structure of Nickel(Ⅱ) Complex with Mono-Schiff Bases from Picolinaldehyde N-Oxide and 1,2-Propanediamine

YAN Shi-Ping, JIANG Zong-Hui, LIAO Dai-Zheng, WANG Geng-Lin, WANG Ru-Ji, WANG Hong-Gen, YAO Xin-Kan   

  1. Department of Chemistry, Center of Laboratory, Nankai University, Tianjin, 300071
  • Received:1991-11-30 Revised:1992-03-30 Online:1992-11-24 Published:1992-11-24

关键词: 晶体结构, 镍配合物, N-氧化吡啶衍生物

Abstract: The crystal structure of nickel(Ⅱ)complex of mono-schiff bases from picolinaldehyde N-oxide and 1,2-propanediamine was determined by X-ray diffraction.The crystal belongs to monoclinic system,space group P21/c,a=0.8199(1)nm,b=3.364(3)nm,c=0.9325(2)nm,β=97.32(2)°,V=2.551 nm3,M=616.04,Z=4,Dx=1.57 g/cm3,μ=10.33 cm-1,F(000)=1272,R=0.068.The coordination number of Ni(Ⅱ)is six.Ni(Ⅱ)ion in the complex is in octahedral environment of coordination.

Key words: Crystal structure, Ni(Ⅱ) Complex, Derivative of pyridine N-oxide

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