模拟细胞色素P-450的仿生氧化反应研究(Ⅷ)——附加有机配体对TPPFe(Ⅲ)Cl催化羟化环己烷的性能影响

高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (10): 1144.

模拟细胞色素P-450的仿生氧化反应研究(Ⅷ)——附加有机配体对TPPFe(Ⅲ)Cl催化羟化环己烷的性能影响

朱申杰, 桂明德, 郭灿城

南开大学化学系

收稿日期:1989-04-21 出版日期:1990-10-24 发布日期:1990-10-24
通讯作者: 朱申杰, 邮编: 300071
基金资助:
国家自然科学基金

Studies on the Biomimetic Oxidation Catalyzed by the Model Compound of Cytochrome P- 450 ( Ⅷ )——The Influence of Additive Organo-Ligand upon the Catalytic Characteristics of TPPFe( Ⅲ )CI in the Hydroxylation of Cyclohexane by PhIO

Zhu Shenjie, Gui Mingde, Guo Cancheng

Department of Chemistry, Nankai Unviersity, Tianjin

Received:1989-04-21 Online:1990-10-24 Published:1990-10-24

摘要/Abstract

摘要： 有机配体如吡啶、咪唑等在TPPFe(Ⅲ)Cl,溶液中能分别形成TPPFe(Ⅲ)(L)Cl六配位配合物和TPPFe(Ⅲ)(L)₂⁺Cl^-六配位络离子盐^[1],洪华华^[2]等曾报道咪唑类有机配体的加入可提高环己烷在抗坏血酸-O₂-TPPFe(Ⅲ)Cl催化羟化反应体系中的环己醇产率。

关键词: 有机配体影响, TPPFe(Ⅲ)Cl催化, 仿生羟化反应

Abstract: The influence of some additive organo-ligands——pyridine, pyrrole thiophene, furan, imi-dazole and Ph₃P upon the catalytic characteristics of TPPFe( Ⅲ )Cl in the hydroxylation of cyclohex-ane by PhIO was reported in this paper.The electronic and steric substituent effects of substituted pyridines on the catalytic activity of TPPFe( Ⅲ )Cl in the above reactions were also studied.

Key words: The influence of organo-ligand, The catalytic characteristics of TPPFe( Ⅲ )Cl, Biomimetic hydroxylation

TrendMD:

朱申杰, 桂明德, 郭灿城. 模拟细胞色素P-450的仿生氧化反应研究(Ⅷ)——附加有机配体对TPPFe(Ⅲ)Cl催化羟化环己烷的性能影响. 高等学校化学学报, 1990, 11(10): 1144.

Zhu Shenjie, Gui Mingde, Guo Cancheng. Studies on the Biomimetic Oxidation Catalyzed by the Model Compound of Cytochrome P- 450 ( Ⅷ )——The Influence of Additive Organo-Ligand upon the Catalytic Characteristics of TPPFe( Ⅲ )CI in the Hydroxylation of Cyclohexane by PhIO. Chem. J. Chinese Universities, 1990, 11(10): 1144.