高等学校化学学报

高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (10): 1138.

• 研究简报 • 上一篇    下一篇

敌鼠钠盐-Triton X-100荧光光度法测定铕

司志坤, 朱贵云, 朱文婧   

  1. 山东大学应用化学系
  • 收稿日期:1989-06-01 出版日期:1990-10-24 发布日期:1990-10-24
  • 通讯作者: 司志坤, 邮编: 250100

Determination of Europium by DPN-Triton X-100 Fluorescence System

Si Zhikun, Zhu Guiyun, Zhu Wenjing   

  1. Department of Applied Chemistry, Shangdong University, Jinan
  • Received:1989-06-01 Online:1990-10-24 Published:1990-10-24

PDF (PC)

被引次数

14

摘要： 敌鼠是一种广泛应用的高效抗凝血类杀鼠剂,其化学名称为2-(2,2-二苯基乙酰基)-1,3-茚满二酮,结构式为: 其钠盐(简称为DPN)作为β-双酮试剂用于荧光分析，未见文献报道。

关键词: 铕, 敌鼠钠盐, 荧光分析

Abstract: Anew fluorescence system of Eu-DPN-NH3-Triton X-100 is investigated in this paper. The optimum conditions to form the system are as follows: concentration of DPN is equal to 5. 0×10-6 mol/L, Triton X-1000. 01% and pH = 9. 0. The fluorescence intensity is a linear function of the concentration of europium at the range of 1. 0× 10-8-8.0× 10-7 mol/L. The method can be used for spectrofluorimetric determination of Eu3+ in a aqueous solution and the detection limit is 6. 0× 10-11 mol/L (9. 1× 10-3 ng/mL). Several samples were analyzed with satisfactory results.

Key words: Europium, Diphacinone, Fluorescence analysis

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