荧光素-层状双金属氢氧化物复合体的发光性能及对Fe3+的荧光识别

doi:10.7503/cjcu20180873

高等学校化学学报 ›› 2019, Vol. 40 ›› Issue (7): 1352.doi: 10.7503/cjcu20180873

• 研究论文: 无机化学 • 上一篇下一篇

荧光素-层状双金属氢氧化物复合体的发光性能及对Fe³⁺的荧光识别

梁足培¹, 苏飞飞², 国荣², 唐昱垚^2,^*, 金烁^2,^*, 于梓洹², 李建¹(), 马淑兰²()

1. 潍坊学院化学化工与环境工程学院, 潍坊 261061
2. 北京师范大学化学学院, 北京 100875

收稿日期:2018-12-28 出版日期:2019-07-10 发布日期:2019-07-12
通讯作者: 唐昱垚,金烁 E-mail:ljwfu@163.com;mashulan@bnu.edu.cn
作者简介:李建, 女, 副教授, 主要从事功能材料的制备与应用研究. E-mail: ljwfu@163.com; 马淑兰, 女, 博士, 教授, 主要从事层状复合材料合成与性质研究. E-mail: mashulan@bnu.edu.cn; * 唐昱垚和金烁目前所在单位为北京市第五十五中学.
基金资助:
山东省自然科学基金(批准号: ZR2015BL024)、国家自然科学基金(批准号: U1832152)和北京市自然科学金(批准号: 2182029)资助.

Photoluminescence Property of Layered Double Hydroxide Composite with Fluorescein and Detection Towards F $e 3 + †$

LIANG Zupei¹, SU Feifei², GUO Rong², TANG Yuyao², JIN Shuo², YU Zihuan², LI Jian^1,^*(), MA Shulan^2,^*()

1. Chemistry & Chemical and Environmental Engineering College, Weifang University, Weifang 261061, China
2. College of Chemistry, Beijing Normal University, Beijing 100875, China

Received:2018-12-28 Online:2019-07-10 Published:2019-07-12
Contact: LI Jian,MA Shulan E-mail:ljwfu@163.com;mashulan@bnu.edu.cn
Supported by:
† Supported by the Natural Science Foundation of Shandong Province, China(No.ZR2015BL024), the National Natural Science Foundation of China(No. U1832152) and the Natural Science Foundation of Beijing, China(No. 2182029).

摘要/Abstract

摘要：

采用离子交换法合成了FLN/OS-LDH复合体(FLN: 荧光素, OS: 1-辛烷磺酸钠, LDH: 镁铝型层状双金属氢氧化物), 并研究了其光致发光和对Fe³⁺的识别性能. 固态时, FLN不发光, 而FLN/OS-LDH复合体呈黄绿色荧光(发射波长为565 nm), 是荧光素(FLN)的特征发射光. 在甲酰胺(FM)中可将该复合体方便剥离为胶状悬浮液, 其发射波长发生蓝移, 为绿光发射(531 nm). 研究了复合体剥离液对金属离子的荧光识别特性, 发现其对Fe³⁺的选择性识别能力很强, 远优于其它离子(Mg²⁺, Ni²⁺, Co²⁺, Cu²⁺, Zn²⁺, Pb²⁺, Cd²⁺和Hg²⁺). 该复合体与Fe³⁺结合发生荧光猝灭现象, 可将其用作检测Fe³⁺的荧光传感器. Fe³⁺检测限为1.27×10^-7 mol/L, 猝灭常数(K_sv)为3.44×10² L/mol.

关键词: 荧光素, 层状双金属氢氧化物, 荧光化学传感, Fe³⁺识别

Abstract:

FLN/OS-LDH composite(FLN is fluorescein, OS is 1-octane sulfonic acid sodium, and LDH is MgAl layered double hydroxide) was synthesized via ion-exchange method and the photoluminescence and detection for Fe(Ⅲ) was tested. In solid state, the FLN/OS-LDH composite displayed yellowish green emission(565 nm) arising from organic FLN. In formamide(FM), the FLN/OS-LDH can be feasily delaminated into colloidal suspention, and showed blue-shifted green emission(ca. 531 nm). The recognition ability of the FLN/OS-LDH for metal cations was researched. The delaminated FLN/OS-LDH colloid in formamide exhibited high selectivity for Fe³⁺ over other ions(Mg²⁺, Ni²⁺, Co²⁺, Cu²⁺, Zn²⁺, Mn²⁺, Pb²⁺, Cd²⁺, and Hg²⁺) with obvious fluorescence quenching, which can work as a kind of effective fluorescence sensor for detection of Fe³⁺. The detection limit of Fe³⁺ is determined to be 1.27×10^-7 mol/L and the quenching constant(K_sv) is 3.44×10² L/mol.

Key words: Fluorescein, Layered double hydroxide(LDH), Fluorescence chemosensor, Detection of Fe³⁺

中图分类号:

O614

TrendMD:

梁足培, 苏飞飞, 国荣, 唐昱垚, 金烁, 于梓洹, 李建, 马淑兰. 荧光素-层状双金属氢氧化物复合体的发光性能及对Fe³⁺的荧光识别. 高等学校化学学报, 2019, 40(7): 1352.

LIANG Zupei, SU Feifei, GUO Rong, TANG Yuyao, JIN Shuo, YU Zihuan, LI Jian, MA Shulan. Photoluminescence Property of Layered Double Hydroxide Composite with Fluorescein and Detection Towards F $e 3 + †$ . Chem. J. Chinese Universities, 2019, 40(7): 1352.

图/表 9

Fig.1 Arrangements of gallery species in NO3-LDH precursor(A) and FLN0.02/OS0.98-LDH composite(B)

Fig.2 XRD patterns of NO3-LDH precursor(a) and FLN/OS-LDH composite(b)The d-values are given in nanometers. Inset is the partial enlarged curve b.

Fig.3 FTIR spectra of FLN-Na(a), OS(b), NO3-LDH(c) and FLN/OS-LDH composite(d)

Fig.4 SEM images of precursor NO3-LDH(A) and FLN/OS-LDH composite(B)

Fig.5 Emission spectra of FLN-Na(a)and FLN/OS-LDH composite(b) in solid state(λex = 510 nm)

Fig.6 Emission spectra of FLN-Na(a) and delaminated FLN/OS-LDH(b) in FMa. λex=460 nm, 0.05 g FLN-Na dissolved in 20 mL FM; b. λex=460 nm, 0.05 g FLN/OS-LDH was dispersed in 20 mL FM.

Fig.7 Emission spectra of FLN/OS-LDH colloid mixed with various metal ionsλex = 460 nm.

Fig.8 Emission spectra of FLN/OS-LDH in FM with addition of 0.018—18 mmol/L Fe3+

Fig.9 Plot of I0/I dependence(0—0.4 mmol/L) on Fe3+ concentration of FLN/OS-LDH colloid in FM at 524 nm emission

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荧光素-层状双金属氢氧化物复合体的发光性能及对Fe³⁺的荧光识别

Photoluminescence Property of Layered Double Hydroxide Composite with Fluorescein and Detection Towards F $e 3 + †$

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