Fe3O4/聚苯乙烯纳米复合材料的结构与性能

doi:10.7503/cjcu20140646

摘要/Abstract

摘要：

采用油酸(OA)表面改性的粒径均一的Fe₃O₄纳米粒子(OA-Fe₃O₄)与工业化聚苯乙烯(PS)通过溶液共混挥发干燥方法得到了具有超顺磁性的OA-Fe₃O₄/PS纳米复合材料. 透射电子显微镜表征结果表明, 在OA-Fe₃O₄质量分数为1%~10%时, OA-Fe₃O₄纳米粒子均匀分散在PS聚合物基体中. 示差扫描量热分析表明, 随着纳米粒子加入量的增加, 纳米复合材料的玻璃化转变温度逐渐降低. 热失重分析表明, OA-Fe₃O₄的存在显著提高了PS在空气条件下的热稳定性. 流变分析表明, 随着纳米粒子加入量的增加(0~10%), 复合材料黏度逐渐降低. 进一步研究了分子量双峰分布的PS与OA-Fe₃O₄纳米复合体系的流变行为, 结果表明, 当PS基体的平均分子量大于临界缠结分子量, 且填充的纳米粒子的半径小于双峰分布PS的均方旋转半径时, 加入纳米粒子仍然导致体系的复合黏度降低.

关键词: 聚苯乙烯, Fe3O4, 纳米粒子, 纳米复合材料, 油酸改性Fe3O4纳米粒子

Abstract:

Oleic acid modified Fe₃O₄ nanoparticles(OA-Fe₃O₄) with uniform particle size were blended with polystyrene(PS) by solution-mixing/evaporation drying method. The resultant PS/Fe₃O₄ nanocomposites exhibited superparamagnetic property. It was found that OA-Fe₃O₄ nanoparticles were well dispersed in PS matrix, when the content of OA-Fe₃O₄ was 1%—10%(mass fraction). Differential scanning calorimetry(DSC) analysis showed that the glass transition temperature(T_g) of PS nanocomposites decreased with the increase of the amount of Fe₃O₄ nanoparticles. According to the results from thermal gravimetric analysis(TGA), the presence of OA-Fe₃O₄ would significantly enhance the thermal stability of PS under air condition. Rheological analysis showed that the melt viscosity of PS nanocomposites decreased with the increase of the amount of nanoparticles(0—10%). Furthermore, we also found that the viscosity reduction took place in the PS with bimodal distribution after adding OA-Fe₃O₄, when the average molecular weight of PS was higher than critical entanglement molecular weight of PS and the radius of nanoparticles was smaller than PS’s mean-square radius of gyration.

Key words: Polystyrene, Fe3O4, Nanoparticles, Nanocomposite, Oleic acid modified Fe3O4 nanoparticles

中图分类号:

O631

TrendMD:

张志杰, 唐涛. Fe₃O₄/聚苯乙烯纳米复合材料的结构与性能. 高等学校化学学报, 2014, 35(11): 2472.

ZHANG Zhijie, TANG Tao. Structure and Properties of Fe₃O₄/Polystyrene Nanocomposites^†. Chem. J. Chinese Universities, 2014, 35(11): 2472.

图/表 14

Fig.1 X-Ray diffraction pattern of OA-Fe3O4 nanoparticles

Fig.2 TEM image of OA-Fe3O4 nanoparticles(A) and particle size distribution(B)

Fig.3 FTIR spectra of pure oleic acid(a) and OA-Fe3O4 nanoparticles(b)

Fig.4 Thermogravimetric analysis of OA-Fe3O4 nanoparticles in N2

Fig.5 TEM images of PS nanocomposites with particle loading of 1%(A), 3%(B), 5%(C), 8%(D) and 10%(E)

Fig.6 DSC curves of pure PS and PS nanocomposites

Table 1 TGA data under nitrogen condition for pure PS and PS nanocomposites

Sample	T_ini/℃	T_max/℃	Residue at 600 ℃(%)
Pure PS	378.9	420.2	0
1%NPs	384.3	424.3	0.1
3%NPs	384.8	424.8	0.3
5%NPs	393.0	425.7	0.5
8%NPs	393.1	426.6	1.0
10%NPs	393.9	429.6	1.6

Table 2 TGA data under air condition for pure PS and PS nanocomposites

Sample	T_ini/℃	T_max/℃	Residue at 600 ℃(%)
Pure PS	312.1	401.9	0
1%NPs	327.2	410.7	0.2
3%NPs	353.4	410.5	0.6
5%NPs	353.7	411.9	1.4
8%NPs	354.3	412.1	1.8
10%NPs	360.2	418.0	2.4

Fig.7 Hysteresis loop of PS nanocomposites with different particle loadings at room temperature

Table 3 Summary of the magnetic parameters

Sample	10² M_S/(A·m²·kg^-1)	10⁵ M_R/(A·m²·kg^-1)	10² H_c/(A·m^-1)
1%NPs	0.81	6.1	1.17
3%NPs	1.75	7.1	2.21
5%NPs	3.09	10.5	5.59
8%NPs	3.86	80.0	12.83
10%NPs	4.67	120.0	14.82

Fig.8 Complex viscosity(η*)(A), storage modulus(G')(B) and loss modulus(G″)(C) as a function of frequency for pure PS and PS nanocomposites

Fig.9 TEM images of PS nanocomposites with a particle loading of 5% (A) PS1; (B) 5PS1-5PS2.

Fig.10 DSC curves of pure PS and PS nanocomposites (second heating)

Fig.11 Complex viscosity(η*)(A), storage modulus(G')(B) and loss modulus(G″)(C) as a function of frequency for pure PS and PS nanocomposites

参考文献 32

[1]	Wang F., Pauletti G. M., Wang J. T., Zhang J. M., Ewing R. C., Wang Y. L., Shi D. L., Adv. Mater., 2013, 25, 3485—3489
[2]	Peng L., Hu L. F., Fang X. S., Adv. Mater., 2013, 25, 5321—5328
[3]	Tang J. J., Li S. Y., Wang Y. H., Tang T., Chinese J. Polym. Sci., 2013, 31(10), 1329—1333
[4]	Li Z. Q., Wang A., Guo C. Y., Hu W. N., Tai Y. F., Chem. J. Chinese Universities,2013, 34(11), 2470—2477
	(李宗群, 汪艾, 郭春燕, 胡文娜, 邰燕芳. 高等学校化学学报,2013, 34(11), 2470—2477)
[5]	Zhang C. N., Wang X. M., New Chemical Materials,2008, 36(11), 42—43
	(张彩宁, 王熙漫. 化工新型材料,2008, 36(11), 42—43)
[6]	Zhang R., Tian Ye., Lv C., Liu L. Q., Liu X. M., Chem. Res. Chinese Universities,2014, 30(3), 343—346
[7]	Schaefer D. W., Justice R. S., Macromolecules,2007, 40, 8501—8517
[8]	Cui S., Canet R., Derre A., Couzi M., Delhaes P., Carbon,2003, 41, 797—809
[9]	Möller M. W., Kunz D. A., Lunkenbein T., Sommer S., Nennemann A., Breu J., Adv. Mater., 2012, 24, 2142—2147
[10]	Song Q. S., Yang Y., Zhu X. F., Chem. J. Chinese Universities,2012, 33(5), 1084—1089
	(宋秋生, 杨洋, 朱小飞. 高等学校化学学报,2012, 33(5), 1084—1089)
[11]	Jiang J. J., Yang C. M., Wang H. B., Liu X. H., Li L. H., Chem. J. Chinese Universities,2014, 35(2), 402—408
	(蒋军军, 杨春明, 王洪波, 刘小华, 李龙浩. 高等学校化学学报,2014, 35(2), 402—408)
[12]	Hyun Y. H., Lim S. T., Choi H. J., Jhon M. S., Macromolecules,2001, 34, 8084—8093
[13]	Ray S. S., Okamoto M., Prog. Polym. Sci., 2003, 28, 1539—1641
[14]	Song Y. S., Youn J. R., Carbon,2005, 43, 1378—1385
[15]	Mackay M. E., Dao T. T., Tuteja A., Ho D. L., Horn B. V., Kim H. C., Hawker C., J. Nat. Mater., 2003, 2, 762—766
[16]	Tuteja A., Mackay M. E., Hawker C. J., Horn B. V., Macromolecules,2005, 38, 8000—8001
[17]	Mackay M. E., Tuteja A., Duxbury P. M., Hawker C. J., Horn B. V., Guan Z., Chen G., Krishnan R. S., Science,2006, 311, 1740—1743
[18]	Tuteja A., Mackay M. E., Narayanan S., Asokan S., Wong M. S., Nano Lett., 2007, 7, 1276—1281
[19]	Einstein A., Ann. Phys., 1905, 17, 549—560
[20]	Einstein A., Ann. Phys., 1906, 17, 371—381
[21]	Tuteja A., Duxbury P. M., Mackay M. E., Macromolecules,2007, 40, 9427—9434
[22]	Park J., An K., Hwang Y., Park J. G., Noh H. J., Kim J. Y., Park J. H., Hwang N. M., Hyeon T., Nat. Mater., 2004, 3, 891—895
[23]	Zhang Z. J., Gong J., Tan H. Y., Yao K., Tang T., Chem. J. Chinese Universities,2014, 35(5), 1080—1085
	(张志杰, 龚江, 谭海英, 姚坤, 唐涛. 高等学校化学学报,2014, 35(5), 1080—1085)
[24]	Wu N. Q., Fu L., Su M., Aslam M., Wong K. C., Dravid V. P., Nano Lett., 2004, 4, 383—386
[25]	Yang K., Peng H. B., Wen Y. H., Li N., Appl. Surf. Sci., 2010, 256, 3093—3097
[26]	He Q. L., Yuan T. T., Zhu J. H., Luo Z. P., Haldolaarachchige N., Sun L. Y., Khasanov A., Li Y. T., Young D. P., Wei S. Y., Guo Z. H., Polymer,2012, 53, 3642—3652
[27]	Panda R. N., Gajbhiye N. S., Balaji G., J. Alloy. Compd., 2001, 326, 50—53
[28]	Sohn B. H., Cohen R. E., Papaefthymiou G. C., J. Magn. Magn. Mater., 1998, 182, 216—224
[29]	Tan H. Y., Xu D. H., Wan D., Wang Y. J., Wang L., Zheng J., Liu F., Ma L., Tang T., Soft Matter,2013, 9, 6282—6290
[30]	Friedrich C., Scheuchenpflug W., Neuhäusler S., Rösch J., J. Appl. Polym. Sci., 1995, 57, 499—508
[31]	Zhu J. H., Wei S. Y., Li Y. T., Sun L. Y., Haldolaarachchige N., Young D. P., Southworth C., Khasanov A., Luo Z. P., Guo Z. H., Macromolecules,2011, 44, 4382—4391
[32]	Lin C. C., Gam S., Meth J. S., Clarke N., Winey K. I., Composto R. J., Macromolecules,2013, 46, 4502—4509

Fe₃O₄/聚苯乙烯纳米复合材料的结构与性能

Structure and Properties of Fe₃O₄/Polystyrene Nanocomposites^†

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 14

参考文献 32

相关文章 15

编辑推荐

Metrics

本文评价

[1]	刘树威, 晋皓, 尹万忠, 张皓. 用于卵巢癌化疗-光热联合治疗的吉西他滨/聚吡咯复合纳米粒子[J]. 高等学校化学学报, 2022, 43(8): 20220345.
[2]	李威, 罗飘, 黄廉湛, 崔志明. 基于聚苯乙烯磺酸的锂金属负极界面保护层的设计[J]. 高等学校化学学报, 2022, 43(8): 20220166.
[3]	王广琦, 毕艺洋, 王嘉博, 石洪飞, 刘群, 张钰. 非贵金属三元复合Ni(PO₃)₂-Ni₂P/CdS NPs异质结的构建及可见光高效催化产氢性能[J]. 高等学校化学学报, 2022, 43(6): 20220050.
[4]	姬发, 刘玲, 余林玲, 孙彦. 黏惰化及酸敏感修饰对纳米粒子黏膜穿透的影响[J]. 高等学校化学学报, 2022, 43(6): 20210837.
[5]	王红, SAN Khin Nyein Ei, 方云, 张鑫宇, 樊晔. Janus纳米金稳定的Pickering乳液界面催化氧化性能[J]. 高等学校化学学报, 2022, 43(6): 20220105.
[6]	陶幸福, 韩成龙, 杨扬, 刘堃. 铝纳米粒子表面引发聚合制备核壳纳米结构[J]. 高等学校化学学报, 2022, 43(10): 20220367.
[7]	初明月, 李峰博, 高宁, 杨昕, 于婷婷, 马慧媛, 杨桂欣, 庞海军. 轮型多金属氧酸盐复合物膜的制备及在检测亚硝酸盐中的应用[J]. 高等学校化学学报, 2022, 43(1): 20210579.
[8]	陈韶云, 张行颖, 刘奔, 田杜, 李奇, 陈芳, 胡成龙, 陈建. Ag纳米粒子在TiO₂四棱柱阵列上的可控生长及其SERS效应[J]. 高等学校化学学报, 2021, 42(8): 2381.
[9]	王昭一, 穆世林, 张学民, 张俊虎. 均一取向等离子体二聚体的制备及光学机理[J]. 高等学校化学学报, 2021, 42(8): 2374.
[10]	王雅雯, 李东, 梁文凯, 孙迎辉, 江林. 表面等离激元金属纳米粒子的多元化结构及应用[J]. 高等学校化学学报, 2021, 42(4): 1213.
[11]	潘菁, 徐敏敏, 袁亚仙, 姚建林. 基于表面增强拉曼光谱快速检测纺织品禁用染料[J]. 高等学校化学学报, 2021, 42(12): 3716.
[12]	孙启睿, 赵楠, 刘树威, 辛华, 张皓, 张乐宁. 用于磁性靶向治疗肺纤维化的聚多巴胺包覆的Fe₃O₄/甲强龙/环磷酰胺复合超粒子[J]. 高等学校化学学报, 2021, 42(10): 3225.
[13]	陈祥云, 朱本强, 袁冰, 于凤丽, 解从霞, 于世涛. 磁性碱木素胺稳定的Ru纳米粒子催化α-蒎烯加氢反应[J]. 高等学校化学学报, 2020, 41(8): 1826.
[14]	宁湫洋, 李万程. 平面型乙醇快速响应气敏传感器的制备[J]. 高等学校化学学报, 2020, 41(8): 1745.
[15]	冷稚华, 李相一. 室温下快速合成超小Fe³⁺掺杂BiF₃纳米粒子[J]. 高等学校化学学报, 2020, 41(8): 1739.