高等学校化学学报

高等学校化学学报 ›› 2013, Vol. 34 ›› Issue (5): 1288.doi: 10.7503/cjcu20120925

• 高分子化学 • 上一篇    下一篇

聚左旋乳酸/聚氧化乙烯共混物的拉伸行为及结构转变

熊祖江1, 张秀芹2, 刘国明1, 赵莹1, 王锐2, 王笃金1   

  1. 1. 中国科学院化学研究所, 北京分子科学国家实验室, 工程塑料院重点实验室, 北京 100190;
    2. 北京服装学院材料科学与工程学院, 服装材料研究开发与评价北京市重点实验室, 北京 100029
  • 收稿日期:2012-10-11 出版日期:2013-05-10 发布日期:2013-05-10
  • 通讯作者: 张秀芹, 女, 副教授, 主要从事生物降解高分子材料研究. E-mail: clyzxq@bift.edu.cn E-mail:clyzxq@bift.edu.cn
  • 基金资助:

    国家自然科学基金(批准号: 50925313, 11179031)和北京市科技新星计划(批准号: 2011016), 新世纪优秀人才(批准号: NCET-12-0601)和北京市教委重点基金(批准号: KZ201310012014)资助.

Crystallization and Tensile Behavior of Poly(L-lactide)/ Poly(ethylene oxide) Blend

XIONG Zu-Jiang1, ZHANG Xiu-Qin2, LIU Guo-Ming1, ZHAO Ying1, WANG Rui2, WANG Du-Jin1   

  1. 1. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
    2. Beijing Key Laboratory of Clothing Materials R & D and Assessment, School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing 100029, China
  • Received:2012-10-11 Online:2013-05-10 Published:2013-05-10

PDF (PC)

被引次数

10

摘要：

采用熔融共混方法制备了聚左旋乳酸(PLLA)和超高分子量聚氧化乙烯(PEO)共混物, 通过差示扫描量热(DSC)、 扫描电子显微镜(SEM)和二维广角X射线散射(2D-WAXS)等方法系统研究了PEO的加入对不同温度下PLLA拉伸行为及拉伸过程中微观结构变化的影响. 结果表明, PLLA/PEO共混物为非均相体系, PEO粒子均匀分布在PLLA中形成两相结构. PEO的加入能够显著降低PLLA的玻璃化转变温度(Tg), 在25～60 ℃范围内显著提高PLLA的拉伸性能. 在60 ℃拉伸时, PEO的加入提高了PLLA在拉伸过程中的结晶和形变能力. 在80 ℃拉伸时, 共混物的拉伸断裂伸长率下降, 但共混物的结晶速度仍高于纯PLLA样品.

关键词: 聚左旋乳酸, 超高分子量聚氧化乙烯, 拉伸性能, 结晶

Abstract:

Poly(L-lactic acid)(PLLA) and PLLA/ultra high molecular weight poly(ethylene oxide)(PEO) blend were prepared by melt-mixing, respectively. The morphology and the stretching behavior as well as their dependence on stretching temperatures of PLLA and PLLA/PEO blend were studied with a combination of differential scanning calorimetry(DSC), scanning electron microscopy(SEM), and in-situ synchrotron wide-angle X-ray scattering(WAXS). The PLLA/PEO blend exhibited phase-separated morphology, with PEO particles as dispersed phase evenly distributed in PLLA matrix. The addition of PEO remarkably decreases the glass transition temperature(Tg) and increases the crystallization rate of PLLA. The fracture strain of PLLA/PEO blend increases drastically under uniaxial stretching at different temperatures of 25—60 ℃. At lower stretching temperature(60 ℃), the crystallization rate and fracture strain of PLLA/PEO blend increase. At higher stretching temperature(80 ℃), the fracture stain of the blend is lower than that of the pure PLLA, while the crystallization rate is still higher than that of PLLA.

Key words: Poly(L-lactic acid), Ultra high molecular weight poly(ethylene oxide), Stretching behavior, Crystallization

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