Cu7.2S4量子点玻璃的制备及三阶非线性光学性质

doi:10.3969/j.issn.0251-0790.2012.08.006

高等学校化学学报 ›› 2012, Vol. 33 ›› Issue (08): 1663.doi: 10.3969/j.issn.0251-0790.2012.08.006

• 研究论文: 无机化学 • 上一篇下一篇

Cu_7.2S₄量子点玻璃的制备及三阶非线性光学性质

赵海军¹, 向卫东^1,2, 钟家松², 杨昕宇¹, 郭玉清², 梁晓娟¹, 黄海宇¹, 罗洪艳¹, 赵秀丽¹, 陈兆平¹

1. 温州大学化学与材料工程学院, 温州 325035;
2. 同济大学材料科学与工程学院, 上海 200092

收稿日期:2011-11-30 出版日期:2012-08-10 发布日期:2012-08-10
通讯作者: 向卫东, 男, 教授, 博士生导师, 主要从事光学材料研究. E-mail: xiangweidong001@126.com E-mail:haijunzhao2008@163.com
基金资助:
国家自然科学基金(批准号: 50772075, 50972107, 51172165); 浙江省自然科学基金(批准号: Y4100233)和浙江省科技创新团队项目(批准号: 2009R50010)资助.

Preparation and the Third-order Optical Nonlinearities of the Sodium Borosilicate Glass Doped with Cu_7.2S₄ Quantum Dots

ZHAO Hai-Jun¹, XIANG Wei-Dong^1,2, ZHONG Jia-Song², YANG Xin-Yu¹, GUO Yu-Qing², LIANG Xiao-Juan¹, HUANG Hai-Yu¹, LUO Hong-Yan¹, ZHAO Xiu-Li¹, CHEN Zhao-Ping¹

1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China;
2. College of Materials Science and Engineering, Tongji University, Shanghai 200092, China

Received:2011-11-30 Online:2012-08-10 Published:2012-08-10

摘要/Abstract

摘要： 利用溶胶-凝胶法结合气氛控制合成了含Cu_7.2S₄量子点的玻璃. 通过热重-差热分析仪对干凝胶样品的热分解机制进行了分析, 并利用X射线粉末衍射仪、 X射线光电子能谱、透射电子显微镜、 X射线能量色散谱)、高分辨透射电子显微镜及选区电子衍射对 Cu_7.2S₄量子点在玻璃中的微结构进行了表征, 利用飞秒Z扫描技术研究了材料在800 nm的三阶非线性光学性质. 结果表明, 尺寸在9~21 nm之间的Cu_7.2S₄纳米晶已经在玻璃中形成, 该玻璃展示出了优异的三阶非线性光学性能, 其三阶非线性光学折射率(γ)、三阶非线性吸收系数(β)和三阶非线性极化率[X⁽³⁾]分别为1.11×10^-15 m²/W, 8.91×10^-9 m/W和9.56×10^-18 m²/V².

关键词: Cu_7.2S₄量子点玻璃, 溶胶-凝胶法, 微结构, 飞秒Z扫描技术

Abstract: Cu_7.2S₄ quantum dots glass was synthesized by both sol-gel and atmosphere control methods. The mechanism thermal decomposition of the stiff gel was studied by means of thermogravimetry-differential thermal analysis. The microstructures of Cu_7.2S₄ quantum dots in the glass were characterized by X-ray powder diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, energy dispersion X-ray spectra, high-resolution transmission electron microscopy, and selected-area electron diffraction. Meanwhile, the third-order nonlinear optical properties of the glass were measured in detail by the femtosecond Z-scan technique at a wavelength of 800 nm. The results show that Cu_7.2S₄ quantum dots have been formed in the glass, and the sizes of these Cu_7.2S₄ quantum dots having the tetragonal crystalline structure ranged from 9 nm to 21 nm, moreover, the glass exhibits the excellent third-order nonlinear optical properties, and the third-order nonlinear optical refractive index(γ), absorption coefficient(β) and susceptibility [X⁽³⁾] of the glass are determined to be 1.11×10^-15 m²/W, 8.91×10^-9 m/W, and 9.56×10^-18 m²/V², respectively. Because of so excellent third-order nonlinear optical properties of the glass doped with Cu_7.2S₄ quantum dots imply that the kind of material will be widely applied in nonlinear optical devices.

Key words: Cu_7.2S₄ quantum dots glass, Sol-gel method, Microstructure, Femtosecond Z-scan technique

中图分类号:

O613.5

TrendMD:

赵海军, 向卫东, 钟家松, 杨昕宇, 郭玉清, 梁晓娟, 黄海宇, 罗洪艳, 赵秀丽, 陈兆平. Cu_7.2S₄量子点玻璃的制备及三阶非线性光学性质. 高等学校化学学报, 2012, 33(08): 1663.

ZHAO Hai-Jun, XIANG Wei-Dong, ZHONG Jia-Song, YANG Xin-Yu, GUO Yu-Qing, LIANG Xiao-Juan, HUANG Hai-Yu, LUO Hong-Yan, ZHAO Xiu-Li, CHEN Zhao-Ping. Preparation and the Third-order Optical Nonlinearities of the Sodium Borosilicate Glass Doped with Cu_7.2S₄ Quantum Dots. Chem. J. Chinese Universities, 2012, 33(08): 1663.

参考文献

[1] Sigman M. B., Ghezelbash A., Hanrath T., Saunders A. E., Lee F., Korgel B. A.. J. Am. Chem. Soc.[J], 2003, 125: 16050-16057 [2] Roy P., Srivastava S. K.. Mater. Chem. Phys.[J], 2006, 95: 235-241 [3] Chen X., Xu H., Xu N., Zhao F., Lin W., Lin G., Fu Y., Huang Z., Wang H., Wu M.. Inorg. Chem.[J], 2003, 42(9): 3100-3106 [4] Meldrum F. C., Flath J., Knoll W.. Langmuir[J], 1997, 13: 2033-2049 [5] Ota J. R., Srivastava S. K.. Nanotechnology[J], 2005, 16: 2415-2419 [6] Albu-Yaron A., Lévy-Clément C., Katty A., Bastide S., Tenne R.. Thin Solid Films[J], 2000, 361/362: 223-228 [7] XIANG Wei-Dong(向卫东), ZHAO Hai-Jun(赵海军), YANG Xin-Yu(杨昕宇), ZHONG Jia-Song(钟家松), LUO Hong-Yan(罗红艳), GUO Yu-Qing(郭玉清), LIANG Xiao-Juan(梁晓娟), YANG Xin-Qi(杨欣琪). Chem. J. Chinese Universities(高等学校化学学报)[J], 2012, 33(2): 230-235 [8] Haeuseler H., Srivastava S. K., Zeit. Kristall.[J], 2000, 215: 205-221 [9] Srivastava S. K., Pramanik M., Palit D., Haeuseler H., Ochel M.. Chem. Mater.[J], 2004, 16: 4168-4173 [10] Couve S., Gouskov L., Szepessy L., Vedel J., Castel E.. Thin Solid Films[J], 1973, 15: 223-231 [11] Nair M. T. S., Guerrero L., Nair P. K.. Semicond. Sci. Technol.[J], 1998, 13: 1164-1169 [12] He Y. B., Polity A., sterreicher I., Pfisterer D., Gregor R., Meyer B. K., Hardt M.. Physica B[J], 2001, 308-310: 1069-1073 [13] Nagcu C., Pop I., Ionescu V., Indrea E., Bratu I.. Mater. Lett.[J], 1997, 32: 73-77 [14] Grozdanov I., Najdoski M.. J. Solid State Chem.[J], 1995, 114: 469-475 [15] Córdova R., Gómez H., Schrebler R., Cury P., Orellana M., Grez P., Leinen D., Ramos-Barrado J. R., Río R. D.. Langmuir[J], 2002, 18: 8647-8654 [16] Lim W. P., Wong C. T., Ang S. L., Low H. Y., Chin W. S.. Chem. Mater.[J], 2006, 18: 6170-6177 [17] Erokhina S., Erokhin V., Nicolini C., Sbrana F., Ricci D., Zitti E. D.. Langmuir[J], 2003, 19: 766-771 [18] Gorai S., Ganguli D., Chaudhuri S.. Cryst. Growth Des.[J], 2005, 5: 875-877 [19] Chen L. F., Yu W., Li Y.. Powder Technol.[J], 2009, 191: 52-54 [20] Li F., Kong T., Bi W. T., Li D. C., Li Z., Huang X. T.. Appl. Surf. Sci.[J], 2009, 255: 6285-6289 [21] Mane R. S., Lokhande C. D.. Mater. Chem. Phys.[J], 2000, 65: 21-31 [22] Liu J., Xue D. F.. J. Cryst. Growth[J], 2009, 311: 500-503 [23] Kuchmii S. Y., Korzhak A. V., Raevskaya A. E., Kryukov A. I.. Theor. Exp. Chem.[J], 2001, 37: 36-41 [24] Sakamoto T., Sunamura H., Kawaura H., Hasegawa T., Nakayama T., Aono M.. Appl. Phys. Lett.[J], 2003, 82: 3032-3034 [25] Chung J. S., Sohn H. J.. J. Power Sources[J], 2002, 108: 226-231 [26] Mao G. Z., Dong W. F., Kurth D. G., Mhwald H.. Nano Lett.[J], 2004, 4: 249-252 [27] Setkus A., Galdikas A., Mironas A., Simkiene I., Ancutiene I., Janickis V., Kaciulis S., Mattogno G., Ingo G. M.. Thin Solid Films[J], 2001, 391: 275-281 [28] Shen X. P., Zhao H., Shu H. Q., Zhou H., Yuan A. H.. J. Phys. Chem. Solids[J], 2009, 70: 422-427 [29] Roy P., Srivastava S. K.. Cryst. Growth Des.[J], 2006, 6: 1921-1926 [30] Xu H. L., Wang W. Z., Zhu W.. Mater. Lett.[J], 2006, 60: 2203-2206 [31] Dutta A., Dolui S. K.. Mater. Chem. Phys.[J], 2008, 112: 448-452 [32] Zhang H. T., Wu G., Chen X. H.. Mater. Chem. Phys.[J], 2006, 98: 298-303 [33] Wang Q., Li J. X., Li G. D., Cao X. J., Wang K. J., Chen J. S.. J. Cryst. Growth[J], 2007, 299: 386-392 [34] Li B. X., Xie Y., Xue Y.. J. Phys. Chem. C[J], 2007, 111: 12181-12187 [35] Wu C., Shi J. B., Chen C. J., Chen Y. C., Lin Y. T., Wu P. F., Wei S. Y.. Mater. Lett.[J], 2008, 62: 1074-1077 [36] Roy P., Srivastava S. K.. Mater. Lett.[J], 2007, 61: 1693-1697 [37] Jiang X. C., Xie Y., Lu J., He W., Zhu L. Y., Qian Y. T.. J. Mater. Chem.[J], 2000, 10: 2193-2196 [38] Thongtem T., Phuruangrat A., Thongtem S.. Curr. Appl. Phys.[J], 2009, 9: 195-200 [39] Cao X. L., Lu Q. F., Xu X. J., Yan J., Zeng H. B.. Mater. Lett.[J], 2008, 62: 2567-2570 [40] Zhu L. Y., Xie Y., Zheng X. W., Liu X., Zhou G. E.. J. Cryst. Growth[J], 2004, 260: 494-499 [41] Tan C. H., Lu R., Xue P. C., Bao C. Y., Zhao Y. Y.. Mater. Chem. Phys.[J], 2008, 112: 500-503 [42] Shen S. L., Zhang Y. J., Peng L., Xu B., Du Y. P., Deng M. J., Xu H. R., Wang Q. B.. CrystEngComm[J], 2011, 13: 4572-4579 [43] Hamzawy E. M. A., Ali A. F.. Mater. Charact.[J], 2006, 57(4/5): 414-418

Cu_7.2S₄量子点玻璃的制备及三阶非线性光学性质

Preparation and the Third-order Optical Nonlinearities of the Sodium Borosilicate Glass Doped with Cu_7.2S₄ Quantum Dots

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