高等学校化学学报

高等学校化学学报 ›› 2012, Vol. 33 ›› Issue (05): 1031.doi: 10.3969/j.issn.0251-0790.2012.05.030

• 物理化学 • 上一篇    下一篇

三维分级结构ZnO的制备及光催化性能

潘超1,3, 董丽2, 邱介山3   

  1. 1. 大连海洋大学理学院, 大连 116023;
    2. 大连民族学院理学院, 大连 116600;
    3. 大连理工大学化工学院, 精细化工国家重点实验室炭素材料研究室, 大连 116024
  • 收稿日期:2011-06-24 出版日期:2012-05-10 发布日期:2012-05-10
  • 作者简介:潘 超, 男, 博士, 副教授, 主要从事静电纺丝功能纳米材料研究. E-mail: pcgy2004@yahoo.com.cn
    邱介山, 男, 博士, 教授, 博士生导师, 主要从事煤基新型纳米炭材料研究. E-mail: jqiu@dlut.edu.cn
  • 基金资助:

    国家自然科学基金(批准号: 50773010, 10705007)、 中国博士后科学基金(批准号: 20100481226)、 东南大学生物电子学国家重点实验室开放基金(批准号: 990170)和大连理工大学精细化工国家重点实验室开放基金(批准号: KF1012)资助.

Fabrication and Photocatalytic Property of Three-dimensional ZnO Hierarchical Structure

PAN Chao1,3, DONG Li2, QIU Jie-Shan3   

  1. 1. College of Science, Dalian Ocean University, Dalian 116023, China;
    2. College of Science, Dalian Nationalities University, Dalian 116600, China;
    3. Carbon Research Laboratory and State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
  • Received:2011-06-24 Online:2012-05-10 Published:2012-05-10

PDF (PC)

被引次数

12

摘要： 以聚乙烯醇/醋酸锌复合纳米纤维为模板, 采用模板辅助共沉积技术制备了三维尖晶石型ZnO纳米线/纳米纤维分级结构, 并采用SEM, XRD对其形貌和晶型结构进行了表征. 在光催化降解乙醛性能实验中, 三维分级结构ZnO表现出比纳米粒子和纤维更好的光催化性能. 这主要归因于ZnO纳米线的次级结构和开放的三维网络结构更有利于乙醛分子和氧分子的扩散和传输, 从而提高了乙醛的光降解速率.

关键词: 氧化锌, 分级结构, 静电纺丝, 共沉积

Abstract: Three-dimensional ZnO hierarchical structures with high densities of secondary ZnO nanowires grown on primary ZnO fibers were fabricated through a co-precipitation reaction growth on the electrospinning PVA/zinc acetate nanofibers template followed by an annealing process in air. The structural analyses showed that as-prepared amorphous ZnC2O4 nanowires converted into wurtzite ZnO after annealing. The morphology of the ZnO hierarchical structures could be further controlled by adjusting the molar ratio of H2C2O4 to EtOH. The hierarchical structured ZnO sample shows an enhanced photocatalytic performance compared with the other nanostructured ZnO powders of nanoparticles, and nanofibers, which can be attributed to the special structural feature with an open and secondary ZnO nanowire that significantly facilitates the diffusion and mass transportation of acetaldehyde molecules and oxygen species in photochemical reaction of acetaldehyde degradation.

Key words: ZnO, Hierarchical structure, Electrospinning, Co-precipitation

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