Syntheses, Structure and SAR Study on Sulfonylurea Compounds( Ⅱ )——Crystal and Molecular Structure of N-[2-(4-methyl)pyrimdinyl]-2-ethyl carboxylate-benzene sulfonyiurea

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (3): 349.

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Syntheses, Structure and SAR Study on Sulfonylurea Compounds( Ⅱ )——Crystal and Molecular Structure of N-[2-(4-methyl)pyrimdinyl]-2-ethyl carboxylate-benzene sulfonyiurea

LI Zheng-Ming¹, JIA Guo-Feng¹, WANG Ling-Xiu¹, LAI Cheng-Ming², WANG Hong-Gen³, WANG Ru-Ji³

1. National Key Laboratory of Elemento-Organic Chemistry, Elemento-Orgmtic Chemstry Institute, Nankai University, Tianjin, 300071;
2. Department of Chemistry, Nankai University;
3. Central Laboratory of Nankai University

Received:1992-06-18 Revised:1992-11-18 Online:1993-03-24 Published:1993-03-24

Abstract

Abstract: Synthesis and crystal structure of title molecule was reported here.This crystal consists of title molecules with solvent molecules CH₂C_12. It is triclinic, belonging to space group P1 with unit cell parameter a=0.7413(2) nm, 6=0.9166(5) nm, c= 1.6289(5) nm, α=75.97(4)°, β=82.28 (2)° γ=76.22(3)° V=l.039 nm³, Z=2, R=0.067 for 1914 reflections.Molecular structure was discussed.There are three different planes in the molecule, in each of which a conjugated system was formed.The intra-molecule and inter-molecule hydrogen bonds between atoms Nand Hhave been found.

Key words: Sulfonylurea compounds, Crystal structure, Molecular structure

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LI Zheng-Ming, JIA Guo-Feng, WANG Ling-Xiu, LAI Cheng-Ming, WANG Hong-Gen, WANG Ru-Ji. Syntheses, Structure and SAR Study on Sulfonylurea Compounds( Ⅱ )——Crystal and Molecular Structure of N-[2-(4-methyl)pyrimdinyl]-2-ethyl carboxylate-benzene sulfonyiurea[J]. Chem. J. Chinese Universities, 1993, 14(3): 349.

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Syntheses, Structure and SAR Study on Sulfonylurea Compounds( Ⅱ )——Crystal and Molecular Structure of N-[2-(4-methyl)pyrimdinyl]-2-ethyl carboxylate-benzene sulfonyiurea

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