Mechanism of Chromium Poisoning of LSM Cathode in Solid Oxide Fuel Cell

Chem. J. Chinese Universities

• 研究简报 • Previous Articles Next Articles

Mechanism of Chromium Poisoning of LSM Cathode in Solid Oxide Fuel Cell

FU Chang-Jing¹, SUN Ke-Ning²*, ZHANG Nai-Qing¹, ZHOU De-Rui¹

1. Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China;
2. Department of Materials Science & Engineering , Beijing Normal University, Beijing 100875, China

Received:2007-01-29 Revised:1900-01-01 Online:2007-09-10 Published:2007-09-10
Contact: SUN Ke-Ning

Abstract

Abstract: Although metallic interconnects have many advantages, the formation of Cr₂O₃ scale and the evaporation of Cr(Ⅵ) species from alloys will greatly degrade the solid oxide fuel cell(SOFC) performance. In this paper, the electrochemical impedance spectroscopy(EIS) and the cathode polarization method of galvanostatic current interruption were employed to investigate the deposition mechanism of chromium with the electrochemical behavior of LSM cathode in the presence of chromia-forming alloys. The results show that the dissociative adsorption and the diffusion of oxygen on the LSM surface were inhibited by the gaseous chromium species and the migration processes of oxygen ions into YSZ electrolyte were inhibited by the solid chromium species deposited on the YSZ surface.

Key words: Solid oxide fuel cell, Chromium, Cathode, La_0.8Sr_0.2MnO_3-δ

CLC Number:

O643.36+2

TrendMD:

FU Chang-Jing¹, SUN Ke-Ning²*, ZHANG Nai-Qing¹, ZHOU De-Rui¹
. Mechanism of Chromium Poisoning of LSM Cathode in Solid Oxide Fuel Cell[J]. Chem. J. Chinese Universities, doi: .

[1]	ZHANG Shiyu, HE Runhe, LI Yongbing, WEI Shijun, ZHANG Xingxiang. Fabrication of Lithium-sulfur Battery Cathode with Radiation Crosslinked Low Molecular Weight of Polyacrylonitrile and the Mechanism of Sulfur Storage [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210632.
[2]	GAO Xiaole, WANG Jiaxin, LI Zhifang, LI Yanchun, YANG Donghua. Synthesis of NiO_x-ZSM-5 Composite Materials and Its Electrocatalytic Hydrogen Evolution Performance in Microbial Electrolysis Cell [J]. Chem. J. Chinese Universities, 2021, 42(9): 2886.
[3]	BAO Junquan, ZHENG Shibing, YUAN Xuming, SHI Jinqiang, SUN Tianjiang, LIANG Jing. An Organic Salt PTO（KPD）₂ with Enhanced Performance as a Cathode Material in Lithium-ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(9): 2911.
[4]	FAN Xiaoyong, WU Yan, SUN Ruibo, GOU Lei, LI Donglin. Construction and Zn Storage Performance of Three Dimensional Porous MnO_x@In₂O₃ Cubes [J]. Chem. J. Chinese Universities, 2021, 42(6): 1816.
[5]	WANG Yimeng, LIU Kai, WANG Baoguo. Coating Strategies of Ni-rich Layered Cathode in LIBs [J]. Chem. J. Chinese Universities, 2021, 42(5): 1514.
[6]	WANG Renheng, XIAO Zhe, LI Yan, SUN Yiling, FAN Shuting, ZHENG Junchao, QIAN Zhengfang, HE Zhenjiang. Synthesis of Li₂FeP₂O₇ Cathode Material at Different Temperatures and Its Electrochemical Performance for Lithium Ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(4): 1299.
[7]	ZHANG Huishuang, GAO Yanxiao, WANG Qiuxian, LI Xiangnan, LIU Wenfeng, YANG Shuting. High-low Temperature Properties of Ni-rich LiNi_0.6Co_0.2Mn_0.2O₂ Cathode Material by Hydrothermal Synthesis with CTAB Assisted [J]. Chem. J. Chinese Universities, 2021, 42(3): 819.
[8]	WU Shuaini, ZHU Pengfei, SHI Huaiqi, LI Na, HU Zhaoxia, CHEN Shouwen. Preparation of CoCr_x/SAPO-34 Catalyst and Its Catalytic Combustion Performance for 1，2-Dichloroethane [J]. Chem. J. Chinese Universities, 2021, 42(12): 3731.
[9]	CUI Jinping, CHEN Wenxian, YU Feifan, CAO Shiyu, LYU Weiyang, YAO Yuyuan. Adsorption Reduction of Hexavalent Chromium and co-Catalytic Degradation of Organic Pollutants by Carbon Doped Hexagonal Boron Nitride Supported MoS₂ [J]. Chem. J. Chinese Universities, 2021, 42(10): 3125.
[10]	HUANG Yongfeng, HUANG Wenting, LIU Wenbao, LIU Yuefeng, LIU Wei, XU Chengjun. Mechanism of Storage and Capacity Attenuation of V₂O₅ as Cathode of Zinc-ion Battery [J]. Chem. J. Chinese Universities, 2020, 41(8): 1859.
[11]	LU Di,ZHENG Chunman,CHEN Yufang,LI Yujie,ZHANG Hongmei. Synthesis of Li-rich Layers/Spinel/Carbon Composite Cathode Materials with Phenol Formaldehyde Resin and Its Electrochemical Performance^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1684.
[12]	LI Xin, CHEN Liang, MA Xiaotao, ZHANG Ding, XU Shoudong, ZHOU Xianxian, DUAN Donghong, LIU Shibin. Preparation of V₂O₃ Hollow Spheres for Lithium Sulfur Batteries ^† [J]. Chem. J. Chinese Universities, 2019, 40(9): 1972.
[13]	YANG Jinge, LI Yujie, LU Di, CHEN Yufang, SUN Weiwei, ZHENG Chunman. Morphology Control and Lithium Storage Performance of Micro/nano Li-rich Cathode Material^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1495.
[14]	YAO Fengnan,LI Yu,FENG Wei. Synthesis and Electrochemical Performance of Carbon-coated FeF₂ Nanocomposite^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1418.
[15]	MA Dongwei,TIAN Runsai,LIU Zhenjiang,FENG Yuanyuan,DING Hongyu,FENG Jijun. Microwave-assisted Synthesis and Electrochemical Performance of Na-Doped Cathode Materials Li_2-_xNa_xMnSiO₄/C^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1280.

Mechanism of Chromium Poisoning of LSM Cathode in Solid Oxide Fuel Cell

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments