Structure and Property Characterization of Dibutyltin Maleate-Styrene-Butyl Acrylate Copolymer

Abstract

Abstract: Benzoic peroxide(BPO) was used as an initiator in bulk terpolymerization of dibutyltin maleate, styrene and butyl acrylate(DBTM-St-BA). The structure and properties of the copolymer were characterized by GPC, IR, ¹H NMR, TGanalysis, Congo red test and dynamic thermoreheological test. The results showed the occurrence of copolymerization. The number-average molecular weight of terpolymer was above 10⁴. The thermal stability and flowability in PVCprocess of copolymer was superior to that of DBTM. It may be used as polyfunctional PVC stabilizer.

Key words: Terpolymer, Structure, Property, Characterization, PVC stabilizer

CLC Number:

O634

TrendMD:

QIAN Qing-Rong, CHEN Qing-Hua, YAN Zhi-Sen, ZHANG Wen-Gong . Structure and Property Characterization of Dibutyltin Maleate-Styrene-Butyl Acrylate Copolymer[J]. Chem. J. Chinese Universities, 2002, 23(3): 504.

[1]	TENG Zhenyuan, ZHANG Qitao, SU Chenliang. Charge Separation and Surface Reaction Mechanisms for Polymeric Single-atom Photocatalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220325.
[2]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[3]	JIANG Bowen, CHEN Jingxuan, CHENG Yonghua, SANG Wei, KOU Zongkui. Recent Progress of Single-atom Materials in Electrochemical Biosensing [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220334.
[4]	WANG Sicong, PANG Beibei, LIU Xiaokang, DING Tao, YAO Tao. Application of XAFS Technique in Single-atom Electrocatalysis [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220487.
[5]	GAO Jian, FENG Yiyu, FANG Wenyu, WANG Hui, GE Jing, FENG Wei. Alkane Grafted Phase Change Azobenzene Materials Based on Low Temperature Heat Release [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220146.
[6]	WU Yushuai, SHANG Yingxu, JIANG Qiao, DING Baoquan. Research Progress of Controllable Self-assembled DNA Origami Structure as Drug Carrier [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220179.
[7]	LI Lin, QI Fenglian, QIU Lili, MENG Zihui. Dynamic Amorphous Photonic Structure Patterns Assembled by Hexagonal Magnetic Nanosheets [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220123.
[8]	LUO Xinyan, JIA Ruonan, XIANG Yong, ZHANG Xiaokun. Progress on the Stretchable Composite Solid Polymer Electrolytes [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220149.
[9]	JIA Yanggang, SHAO Xia, CHENG Jie, WANG Pengpeng, MAO Aiqin. Preparation and Lithium Storage Performance of Pseudocapacitance-controlled Perovskite High-entropy Oxide La（Co_0.2Cr_0.2Fe_0.2Mn_0.2Ni_0.2）O₃ Anode Materials [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220157.
[10]	YANG Dan, LIU Xu, DAI Yihu, ZHU Yan, YANG Yanhui. Research Progress in Electrocatalytic CO₂ Reduction Reaction over Gold Clusters [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220198.
[11]	ZHAO Yingzhe, ZHANG Jianling. Applications of Metal-organic Framework-based Material in Carbon Dioxide Photocatalytic Conversion [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220223.
[12]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[13]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[14]	CHEN Weiqin, LYU Jiamin, YU Shen, LIU Zhan, LI Xiaoyun, CHEN Lihua, SU Baolian. Preparation of Organic Hybrid Mesoporous Beta Zeolite for Alkylation of Mesitylene with Benzyl Alcohol [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220086.
[15]	ZHU Kai, LI Jie, WU Xiaoyi, HU Weiwei, WU Dongmei, YU Chengxiao, GE Zhiwei, YE Xingqian, CHEN Shiguo. Combined PGC-Triple-Tof-MS Enables the Separation， Identification of Sugar Beet Pectin Derived Oligomers [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220023.

Structure and Property Characterization of Dibutyltin Maleate-Styrene-Butyl Acrylate Copolymer

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments