Synthesis and Oxidative Catalysis of Microporous Heteropolyoxometalates CsxH5-xPW10V2O40SiO2

Chem. J. Chinese Universities ›› 2002, Vol. 23 ›› Issue (3): 478.

• Articles • Previous Articles Next Articles

Synthesis and Oxidative Catalysis of Microporous Heteropolyoxometalates Cs_xH_5-xPW₁₀V₂O₄₀SiO₂

PENG Ge¹, HU Chang-Wen¹, WANG Yong-Hui¹, CHEN Li-Dong¹, WANG En-Bo¹, FENG Shou-Hua², LIU Yan-Yong³

1. Institute of Polyoxometalate Chemistry, College of Chemistry, Northeast Normal University, Changchun 130024, China;
2. State Key Laboratory of Inorganic Synthesisand Preparative Chemistry, Jilin University, Changchun 130023, China;
3. Chemical Technology Division, Institute of Research and Innovation, Takada 1201, Kashiwa, Chiba 277, Japan

Received:2001-03-01 Online:2002-03-24 Published:2002-03-24

Abstract

Abstract: Microporous heteropolyoxometalates Cs_xH_5-xPW₁₀V₂O₄₀SiO₂ were synthesized by a solgel technique and characterized by IR, UV-Vis, BETadsorption/desorption isotherm. The structural frameworks of Cs_xH_5-xPW₁₀V₂O₄₀ are preserved within the silica networks. Cs_xH_5-xPW₁₀V₂O₄₀SiO₂ are a kind of polyoxometalatesilica gel hybrids with uniform micropores of ca. 0.65 nm. They show a high catalytic activity for oxidation reaction of benzyl alcohol by H₂O₂(30) in liquid-solid systems and product selectivity for benzaldehyde(>96). The highest activity is observed at x=2.5 in Cs_xH_5-xPW₁₀V₂O₄₀SiO₂ and little formation of benzoic acid and a more deeply oxidized product is observed.

Key words: Microporous heterpolyoxometalates, Synthesis, Structural characterization, Benzylalcohol, Oxidative catalysis, Benzyl aldehyde

CLC Number:

O643

TrendMD:

PENG Ge, HU Chang-Wen, WANG Yong-Hui, CHEN Li-Dong, WANG En-Bo, FENG Shou-Hua, LIU Yan-Yong . Synthesis and Oxidative Catalysis of Microporous Heteropolyoxometalates Cs_xH_5-xPW₁₀V₂O₄₀SiO₂[J]. Chem. J. Chinese Universities, 2002, 23(3): 478.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[3]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[4]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[5]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[6]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[7]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[8]	LI Yidi, TIAN Xiaochun, LI Junpeng, CHEN Lixiang, ZHAO Feng. Electron Transfer on the Semiconductor-microbe Interface and Its Environmental Application [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220089.
[9]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[10]	ZHUANG Jiahao, WANG Dingsheng. Current Advances and Future Challenges of Single-atom Catalysis [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220043.
[11]	FENG Li, SHAO Lanxing, LI Sijun, QUAN Wenxuan, ZHUANG Jinliang. Synthesis of Ultrathin Sm-MOF Nanosheets and Their Visible-light Induced Photodegradation of Mustard Simulant [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210867.
[12]	ZHANG Zhinan, CHENG Haiming, TENG Shiyong, ZHANG Ying. Synthesis and Optical Properties of RbPb₂Cl₅ [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220418.
[13]	XING Peiqi, LU Tong, LI Guanghua, WANG Liyan. Controllable Syntheses of Two Cd（II） Metal-organic Frameworks Possessing Related Structures [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220218.
[14]	WANG Jie, HUO Haiyan, WANG Yang, ZHANG Zhong, LIU Shuxia. General Strategy for In situ Synthesis of NENU-n Series Polyoxometalate-based MOFs on Copper Foil [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210557.
[15]	LIANG Yu, LIU Huan, GONG Lige, WANG Chunxiao, WANG Chunmei, YU Kai, ZHOU Baibin. Synthesis and Supercapacitor Properties of Biimidazole-modified ｛SiW₁₂O₄₀｝ Hybrid [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210556.

Synthesis and Oxidative Catalysis of Microporous Heteropolyoxometalates Cs_xH_5-xPW₁₀V₂O₄₀SiO₂

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments