Hydrothermal Synthesis and Crystal Structure of [In2(HPO3)4]·(NH3CH2CH2NH3)

Chem. J. Chinese Universities

• 研究简报 • Previous Articles Next Articles

Hydrothermal Synthesis and Crystal Structure of [In₂(HPO₃)₄]·(NH₃CH₂CH₂NH₃)

LIU Cheng-Zhan^1,2, ZHU Guang-Shan¹, FANG Qiang-Rong¹, XUE Ming¹, SUN Fu-Xing¹, QIU Shi-Lun¹*

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China;
2. Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

Received:2006-12-27 Revised:1900-01-01 Online:2007-09-10 Published:2007-09-10
Contact: QIU Shi-Lun

Abstract

Abstract: A new three-dimensional indium phosphite, [In₂(HPO₃)₄]·(NH₃CH₂CH₂NH₃), was prepared under hydrothermal conditions via using ethylenediamine as a template. Its structure was solved by singlecrys-tal X-ray diffraction. The compound crystallizes in a monoclinic system, space group P2/n, with cell parameters a=0.91405(5) nm, b=0.91984(5) nm, c=0.96120(5) nm, β=115.9950(10)°, V=0.72640(7) nm³, Z=2, R₁=0.0249, wR₂=0.0650, GOF=1.044. The inorganic topological structure is built up from the vertex linking of InO₆ octahedral and HPO₃ pyramidal tetrahedral units, forming eight-membered ring channels along the [506] direction. The diprontonated ethylenediamine molecules are entrapped in eight-membered ring channels.

Key words: Hydrothermal synthesis, Crystal structure, Ethylenediamine, Indium phosphite

CLC Number:

O614.37

TrendMD:

LIU Cheng-Zhan^1,2, ZHU Guang-Shan¹, FANG Qiang-Rong¹, XUE Ming¹, SUN Fu-Xing¹, QIU Shi-Lun¹*. Hydrothermal Synthesis and Crystal Structure of [In₂(HPO₃)₄]·(NH₃CH₂CH₂NH₃)[J]. Chem. J. Chinese Universities, doi: .

[1]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[2]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[3]	LIANG Yu, LIU Huan, GONG Lige, WANG Chunxiao, WANG Chunmei, YU Kai, ZHOU Baibin. Synthesis and Supercapacitor Properties of Biimidazole-modified ｛SiW₁₂O₄₀｝ Hybrid [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210556.
[4]	YUE Shengli, WU Guangbao, LI Xing, LI Kang, HUANG Gaosheng, TANG Yi, ZHOU Huiqiong. Research Progress of Quasi-two-dimensional Perovskite Solar Cells [J]. Chem. J. Chinese Universities, 2021, 42(6): 1648.
[5]	ZHANG Huishuang, GAO Yanxiao, WANG Qiuxian, LI Xiangnan, LIU Wenfeng, YANG Shuting. High-low Temperature Properties of Ni-rich LiNi_0.6Co_0.2Mn_0.2O₂ Cathode Material by Hydrothermal Synthesis with CTAB Assisted [J]. Chem. J. Chinese Universities, 2021, 42(3): 819.
[6]	WANG Ye, ZHANG Xiaosi, SUN Lijing, LI Bing, LIU Lin, YANG Miao, TIAN Peng, LIU Zhongyi, LIU Zhongmin. Morphology Control of SAPO Molecular Sieves under the Assistance of Organosilane [J]. Chem. J. Chinese Universities, 2021, 42(3): 683.
[7]	WANG Jianyu, ZHANG Qiang, YAN Wenfu, YU Jihong. Roles of Hydroxyl Radicals in Zeolite Synthesis [J]. Chem. J. Chinese Universities, 2021, 42(1): 11.
[8]	WU Qinming, WANG Yeqing, MENG Xiangju, XIAO Fengshou. Reconsideration of Crystallization Process for Aluminosilicate Zeolites [J]. Chem. J. Chinese Universities, 2021, 42(1): 21.
[9]	LIU Yabing,LI Mingyang,TIAN Ge,ALATENG Shaga,PEI Tonghe,NIE Jingsi. Syntheses, Structures and Catalytic Properties of Two Supramolecular Complexes Based on 2-Pyridylamine and Cluster ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 995.
[10]	TIAN Xia,YANG Fuqun,YUAN Wei,ZHAO Lei,YAO Lei,ZHEN Xiaoli,HAN Jianrong,LIU Shouxin. Synthesis, Structure and Recognition Properties of Macrocyclic Crown Ethers with Oxadiazole ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 490.
[11]	ZHUO Mengning,LI Fei,JIANG Hao,CHEN Qianwen,LI Peng,WANG Lizhang. Preparation of SnO₂/GDE Cathodes and Their Electrocatalytic Reduction of CO₂ to Produce Formic Acid ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 530.
[12]	LIU Dongmei,SU Yajing,LI Shanshan,XU Qiwei,LI Xia. Transition Metal Coordination Polymers Constructed by 4-(4-Carboxyphenoxy)isophthalic Acid: Synthesis, Crystal Structure, Fluorescence Sensing and Photocatalysis ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 253.
[13]	DONG Le, HUANG Xingliang, REN Junjie, DAI Xiaoping, LIU Zongyan, TIAN Hongfeng, WANG Zhidong, WU Xiaotong. Influence Mechanism of Particle Size and Distribution of Silica Sol in the Synthesis of Ferrierite Zeolite with High SiO₂/Al₂O₃ Ratio [J]. Chem. J. Chinese Universities, 2020, 41(11): 2449.
[14]	QIN Liulei,LIU Yang,GUAN Xiaoqin,ZHENG Xiaoyuan,ZHANG Ziyu,LIU Zunqi. Synthesis and Switchable Dielectric Properties of an Inorganic-organic Hybrid Complex [H₂(DABCO)CuCl₄]·H₂O ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 70.
[15]	ZHOU Hai, CHEN Hao, GUO Ya, KANG Min. Synthesis of Meso-porous Co₃O₄ Polyhedra and Their Electrochemical Properties^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1374.

Hydrothermal Synthesis and Crystal Structure of [In₂(HPO₃)₄]·(NH₃CH₂CH₂NH₃)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments