Chem. J. Chinese Universities

• 研究简报 • Previous Articles     Next Articles

High Temperature Synthesis of NaY Zeolite

XIONG Xiao-Yun, LI Cai-Jin, DING Hong, HUANG Shi-Ying, LIANG De-Sheng, XIAO Feng-Shou, LI Shou-Gui*   

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China
  • Received:2007-01-23 Revised:1900-01-01 Online:2007-09-10 Published:2007-09-10
  • Contact: LI Shou-Gui

Abstract: This work describes a novel method to synthesize NaY zeolite at high temperature(100—140 ℃) by using NaY seeds solution as a silica source, which is also a method for the activation of silica source in the synthesis of NaY zeolite. Conventionally, the synthesis temperature of NaY zeolite from water glass is about 100 ℃, and higher temperature(>100 ℃) leads to the formation of impurity. However, this work shows that high-temperature synthesis(100—140 ℃) still exhibits a pure phase NaY. It is very interesting that, compared with conventional temperature, high-temperature in the synthesis of NaY zeolite has obvious advantages such as short crystallization time and high n(Si)/n(Al) ratio in the product. More importantly, this method is possible to extend to the synthesis of NaA, NaX, Ω, ECR-1and MOR.

Key words: NaY zeolite, Activation of silica source, Guidance agent of crystallization

CLC Number: 

TrendMD: