Chem. J. Chinese Universities

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Preparation and Characterization of ZnS∶Mn/PVA Composite Nanofibers via Electrospinning

WANG Hai-Ying, YANG Yang, LU Xiao-Feng, WANG Ce
  

  1. Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, China
  • Received:2005-12-07 Revised:1900-01-01 Online:2006-09-10 Published:2006-09-10
  • Contact: WANG Ce

Abstract: ZnS∶Mn/poly(vinyl alcohol)(PVA) composite nanofibers were successfully prepared by using electrospinning technique and gas-solid reaction. The composites were characterized by means of TEM, SEM, FTIR, XRD, UV, PL measurements. The results indicate that the Mn\|doped ZnS nanocrystals with diameter about 3 nm were well-dispersed in PVA nanofibers through the coordination between —OH and Zn2+∶Mn, which prevented the ZnS∶Mn nanoparticles from aggregating in the nanofibers. Furthermore, the PL measurement demonstrates that the luminescence properties of Mn-doped samples changed significantly compared with the un-doped sample, which was caused by the influence of Mn centers.

Key words: Electrospinning, ZnS∶Mn nanoparticles, Poly(vinyl alcohol), Nanofiber

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