Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (5): 808.

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Syntheses and Optical Properties of Alkoxylneodymium-Containing Copolymers

WANG Liao-Hui, ZHANG Wen-Gong   

  1. Institute of Polymer Science, Fujian Normal University, Fuzhou 350007
  • Received:1995-04-17 Online:1996-05-24 Published:1996-05-24

Abstract: For increasing in the transmittancy of rare earth metal-containing polymer,ten alkoxylneodymium-containing monomers, which have good compatibility with MMA,are synthesized by the reactions of neodymium alkoxides with maleic anhydride.Then ten alkoxylneodymium-containing copolymers are prepared by the copolymerizatons of these monomers with MMAusing AIBNas an initiator.Studies on optical properties of these copolymers indicate that, in comparison with PMMA, alkoxylneodymium-containing copolymers have higher transmittancy and refractive indexes,and their refractive indexes increase linearly with increasing Nd content.Moreover, they have Nd3+) ion characteristic light selective absorbability.So they may be a series of new type optical plastics.

Key words: Rare earth metal-containing polymer, Alkoxylneodymium-containing copolymers, Synthesis, Optical property

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