Fabrication of Supramolecular Nanotubes Based on Barbituric Acid and Melamine Derivatives

Abstract

Abstract: Hollow supramolecular nanotubes have been fabricated by the self-assembling of 5-(4-N-methyl-N-tetradecyl aminobenzylidene)-2,4,6 (1H,3H)-pyrimidinetrione(AB_1,14) and 4-amino-2, 6-didodecylamino-1,3,5-triazine (M₁₂) in non hydrous chloroform. The nanotubes are 7 nm in diameter and about hundreds of nanometer in length. Their formation was realized by π-π aromatic stacking of the hexamers, which resulted from the interaction of three complementary hydrogen bonds between AB_1,14 and M₁₂. X-ray diffraction pattern indicated that the distance between the hexamers is 0.49 nm.

Key words: Self-assembling, Nanotube, Barbituric acid, Melamine

CLC Number:

O643

TrendMD:

LU Nan, LU Ran, WANG Ce, CAO Chang-Sheng, XIE Teng-Feng, LI Tie-Jin . Fabrication of Supramolecular Nanotubes Based on Barbituric Acid and Melamine Derivatives[J]. Chem. J. Chinese Universities, 2000, 21(3): 466.

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Fabrication of Supramolecular Nanotubes Based on Barbituric Acid and Melamine Derivatives

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