Chem. J. Chinese Universities ›› 2025, Vol. 46 ›› Issue (9): 20250098.doi: 10.7503/cjcu20250098
• Polymer Chemistry • Previous Articles Next Articles
YANG Bing1, DING Xia1, XU Jun2, LI Ye3, GU Rui2, ZHANG Hui1, HOU Zhaosheng2()
Received:
2025-04-03
Online:
2025-09-10
Published:
2025-07-07
Contact:
HOU Zhaosheng
E-mail:houzs@sdnu.edu.cn
Supported by:
CLC Number:
TrendMD:
YANG Bing, DING Xia, XU Jun, LI Ye, GU Rui, ZHANG Hui, HOU Zhaosheng. Robust, Self-healing Polyurethane Hydrogel Enabled by Dual Crosslinking of Dynamic Disulfide and Hydrogen Bonds[J]. Chem. J. Chinese Universities, 2025, 46(9): 20250098.
Sample | n(PEG)/mmol | n(IPDI)/mmol | n(DSO)/mmol | w(DSO)*(%) | w(PEG)*(%) | w(IPDI)*(%) | Solid content(%) | ||
---|---|---|---|---|---|---|---|---|---|
Mn=2000 | Mn=3000 | Mn=4000 | |||||||
SPUG⁃I | 5.0 | — | — | 10.0 | 2.5 | 4.19 | 78.40 | 17.41 | 49.58 |
SPUG⁃II | — | 5.0 | — | 10.0 | 2.5 | 3.01 | 84.48 | 12.51 | 48.64 |
SPUG⁃III | — | — | 5.0 | 10.0 | 2.5 | 2.35 | 87.89 | 9.46 | 49.68 |
SPUG⁃IV | — | — | 5.0 | 9.0 | 2.0 | 1.91 | 89.18 | 8.91 | 48.72 |
Table 1 Basic compositions and component contents of SPUGs
Sample | n(PEG)/mmol | n(IPDI)/mmol | n(DSO)/mmol | w(DSO)*(%) | w(PEG)*(%) | w(IPDI)*(%) | Solid content(%) | ||
---|---|---|---|---|---|---|---|---|---|
Mn=2000 | Mn=3000 | Mn=4000 | |||||||
SPUG⁃I | 5.0 | — | — | 10.0 | 2.5 | 4.19 | 78.40 | 17.41 | 49.58 |
SPUG⁃II | — | 5.0 | — | 10.0 | 2.5 | 3.01 | 84.48 | 12.51 | 48.64 |
SPUG⁃III | — | — | 5.0 | 10.0 | 2.5 | 2.35 | 87.89 | 9.46 | 49.68 |
SPUG⁃IV | — | — | 5.0 | 9.0 | 2.0 | 1.91 | 89.18 | 8.91 | 48.72 |
[18] | Qi Y., Fan H. L., Chem. Res. Chinese Universities, 2024, 40(5), 776—785 |
[19] | Xu B. B., Zhang Y., Li J., Wang B. X., Li R. X., Cheng D. H., Chang G. T., Int. J. Biol. Macromol., 2025, 290, 138811 |
[20] | Maiti S., Maji B., Yadav H., Carbohyd. Polym., 2024, 326, 121584 |
[21] | Liu Y. Y., Song S. R., Liu S. Y., Zhu X. Y., Wang P. G., J. Nanomater., 2022, 2022, 4656037 |
[22] | Zainal S. H., Mohd N. H., Suhaili N., Anuar F. H., Lazim A. M., Othaman R., J. Mater. Res. Technol., 2021, 10, 935—952 |
[23] | Hao T., Niu G., Zhang H., Zhu Y., Zhang C., Kong F., Xu J., Hou Z., J. Mater. Chem. B, 2023, 11, 5846—5855 |
[24] | Wang Y. Q., Quan M. Q., Sha G. Z., Huang J. M., Cui M. H., Li X. Q., Zhu J., Chen J., J. Envir. Chem. Engin., 2025, 13(3), 116131 |
[25] | Dumas J. E., BrownBaer P. B., Prieto E. M., Guda T., Hale R. G., Wenke J. C., Guelcher S. A., Biomed. Mater., 2012, 7, 024112 |
[26] | Liu F., Han R., Naficy S., Casillas G., Sun X., Huang Z., ACS Appl. Nano Mater., 2021, 4, 7988—7994 |
[27] | Xiang S. L., Su Y. X., Yin H., Li C., Zhu M. Q., Nano Energy, 2021, 85, 105965 |
[28] | Fang Y., Xu J., Gao F., Du X., Du Z., Cheng X., Wang H., Compos. Part B Eng., 2021, 219, 108965 |
[29] | Naseri E., Ahmadi A., Eur. Polym. J., 2022, 173, 111293 |
[30] | Mishra P., Kumar H., Sahu S., Jha R., Adv. Mater. Technol., 2023, 8, 2200661 |
[31] | Hou Y. J., Peng Y., Li P., Wu Q., Zhang J. Q., Li W. H., Zhou G. W., Wu J. R., ACS Appl. Mater. Interfaces, 2022, 14, 35097—35104 |
[32] | Teng J., Qu L., Liu Z., Qin Z., Xu J., Wang Z., Hou Z., ACS Appl. Polym. Mater., 2022, 4, 7801—7811 |
[33] | Si P., Jiang F., Cheng Q. S., Rivers G., Xie H., Kyaw A. K. K., Zhao B., J. Mater. Chem., 2020, 8, 25073—25084 |
[34] | Hao T., Gao Y., Zheng E., Yang H., Pan Y., Zhang P., Xu J., Hou Z., Eur. Polym. J., 2024, 220, 113494 |
[35] | Han J. P., Yuan Y., Chen Y. L., Chem. Res. Chinese Universities, 2023, 39(5), 757—762 |
[36] | Guo H. S., Han Y., Zhao W. Q., Yang J., Zhang L., Nat. Commun., 2020, 11, 2037—2046 |
[37] | Zhang K. M., Liu Y. T., Wang Z., Song C. X., Gao C. H., Wu Y. M., Eur. Polym. J., 2020, 134, 109857—109865 |
[38] | Shi Z., Kang J., Zhang L., ACS Appl. Mater. Interfaces, 2020, 12, 23484—23493 |
[39] | Kim S. M., Jeon H., Shin S. H., Park S. A., Jegal J., Hwang S. Y., Oh D. X., Park J., Adv. Mater., 2018, 30(1), 1705145 |
[40] | Sheng Y. M., Cheng B., Lu X., Chem. J. Chinese Universities, 2020, 41(3), 572—581 |
盛叶明, 程波, 卢珣. 高等学校化学学报, 2020, 41(3), 572—581 | |
[41] | Ghorbani R., Saeedi L., Biol. Mol. Chem., 2024, 2, 45—54 |
[42] | Arshad N., Zia K. M., Hussain M. T., Zuber M., Arshad M. M., Polym. Bull., 2022, 79, 7711—7727 |
[43] | Wei K. L., Wu Y., Cao X. J., Yang X. Y., Tang B. M., Deng L., Eur. Polym. J., 2024, 211, 113010 |
[44] | Jin Y., Hu C. C., Wang J., Ding Y. L., Shi J. J., Wang Z. K., Xu S. C., Yuan L., Angew. Chem. Int. Ed., 2023, 62, e202305677 |
[45] | Liu Y., Zhang Z. T., Fan W. W., Yang K. F., Li Z. J., J. Mater. Sci., 2022, 57(9), 5679—5696 |
[46] | Cui Y. Y., Sheng M. Q., Liu Y., Feng Y., Li H. J., Wu Y. C., ACS Appl. Mater. Interfaces, 2023, 15, 58967—58975 |
[47] | Qiao L. Y., Liu C. D., Liu C., Zong L. S., Gu H. J., Wang C. H., Jian X. G., Eur. Polym. J., 2022, 162, 118038 |
[48] | Zhao Z. Z., Qin Z. H., Zhao T. Q., Li Y. Y., Hou Z. S., Hu H., Su X. F., Gao Y. N., Molecules, 2024, 29, 4952 |
[49] | Tang Q. Y., Jiang J., Li J. J., Zhao L., Xi Z. H., Polymers, 2024, 16(9), 1229 |
[50] | Zou F. X., Wang Y. S., Zheng Y. D., Xie Y. J., Zhang H., Chen J. S., Hussain M. I., Meng H. Y., Peng J., Bioact. Mater., 2022, 17, 471—487 |
[51] | Zheng E., Zhang P., Wang J., Chen Y., Liu H., Xu J., Hou Z., Polymer, 2025, 327, 128381 |
[52] | Moffat K. L., Marra K. G., J. Biomed. Mater. Res. Part B: Appl. Biomater., 2004, 71, 181—187 |
[53] | Wessely I. D., Matt Y., An Q., Bräse S., Tsotsalas M., RSC Adv., 2021, 11, 27714—27719 |
[54] | Zahra Q., Minhas M. U., Khan S., Wu P. C., Suhail M., Iqbal R., Bashir M., Polym. Bull., 2022, 79, 5389—5415 |
[55] | Zhao L. J., Xu H., Liu L. C., Zheng Y. Q., Han W., Wang L. L., Adv. Sci., 2023, 10, 2303922 |
[1] | Shan B. H., Wu F. G., Adv. Mater., 2024, 36(5), 2210707 |
[2] | Madduma⁃Bandarage U. S. K., Madihally S. V., J. Appl. Polym. Sci., 2021, 138, 50376 |
[3] | Unal A. Z., West J. L., Bioconjugate Chem., 2020, 31, 2253—2271 |
[4] | Nie J., Pei B., Wang Z., Hu Q., Carbohyd. Polym., 2019, 205, 225—235 |
[5] | McClements D. J., Adv. Colloid Interf., 2024, 332, 103278 |
[6] | Sharma S., Bhende M., Goel A., Polym. Bull., 2024, 81(10), 1—22 |
[7] | Shahriari M. H., Abdouss M., Hadjizadeh A., Polym. Eng. Sci., 2023, 63, 798—810 |
[8] | Shoukat H., Buksh K., Noreen S., Pervaiz F., Maqbool I., Ther. Deliv., 2021, 12, 375—396 |
[9] | Wei X. Y., Liu Z., Fang H. l., Cui Z. Y., He S., Shao W., Polymer, 2025, 14, 128047 |
[10] | Wu Q., Ghosal K., Kana’an N., Roy S., Rashed N., Majumder R., Mandal M., Gao L., Farah S., Bioact. Mater., 2025, 44, 116—130 |
[11] | Wang X. J., Yuan J. Z., Sun N. N., Jiang Y. H., Yu Y. C., Lai G. Q., Yang X. f., Food Control, 2025, 168, 110918 |
[12] | Jiang Y. J., Huang T. D., Cao Y. Y., Bai R. X., Wu J., Wang Z. X., Sun H. M., Chem. J. Chinese Universities, 2024, 45(1), 20230312 |
江云静, 黄童黛, 曹玉玉, 白荣先, 吴杰, 王祖曦, 孙红梅. 高等学校化学学报, 2024, 45(1), 20230312 | |
[13] | Aydin G., Abdullah T., Okay O., Eur. Polym. J., 2025, 223, 113651 |
[14] | Li X., Liu W. K., Li Y. M., Lan W. L., Zhao D. G., Wu H. C., Feng Y., He X. L., Li Z., Li J. H., Luo F., Tan H., J. Mater. Chem. B, 2020, 8, 5117—5130 |
[15] | Cai Z., Zhou W., Chen W. J., Huang R., Zhang R., Sheng L., Shi M. M., Hu Y., Huang C., Chen Y., Food Chem., 2024, 459, 140272 |
[16] | Li M., Zhang Z. Y., Liang Y. P., He J. H., Guo B. L., ACS Appl. Mater. Interfaces, 2020, 12, 35856—35872 |
[17] | Zhang T., Jia X. L., Hou Z. Y., Xie G., Zhang L. B., Zhu J. T., Chem. Res. Chinese Universities, 2023, 39(5), 803—808 |
[56] | Canadell J., Goossens H., Klumperman B., Macromolecules, 2011, 44(8), 2536—2541 |
[57] | Memon H., Wei Y., Zhu C. Y., Mater. Today Commun., 2021, 29, 102814 |
[58] | Sun X. G., Huang X. R., Liang Q. D., Wang N., Zheng X. T., Zhang Q., Yu D. H., Int. J. Biol. Macromol., 2024, 272, 132448 |
[59] | Ding X., Yang B., Hou Z., Molecules, 2024, 29, 5435 |
[60] | Nakajima T., Kurokawa T., Ahmed S., Wu W. L., Gong J. P., Soft Matter, 2013, 9(6), 1955—1966 |
[61] | Xiang Z., Chu C. Z., Xie H., Xiang T., Zhou S. B., ACS Appl. Mater. Interfaces, 2021, 13(1), 1463—1473 |
[62] | Xu Y., Lu G. G., Chen M. Y., Wang P. L., Li Z. L., Han X. W., Liang J., Sun Y., Fan Y. J., Zhang X. D., Carbohyd. Polym., 2020, 250, 116979 |
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