Preparation of Triphenylamine Based PAF-106s via Mechanical Ball Milling and C2 Hydrocarbons Adsorption Property

doi:10.7503/cjcu20210771

Abstract

Abstract:

Using triphenylamine as monomer， FeCl₃ as catalyst， and formaldehyde dimethyl acetal（FDA） as knitting agent， PAF-106s were prepared by mechanical ball milling different molar ratios of triphenylamine， FeCl₃ and FDA. Infrared spectroscopy， elemental analysis， X-ray photoelectron spectroscopy， and solid state nuclear magnetic field（NMR） proved that polymerization had taken place. N₂ adsorption results showed that the ratio of triphenylamine， FeCl₃ and FDA could affect the porous properties of PAF-106s. When the ratio of FeCl₃ to tripheny? lamine increased from 3∶1 to 12∶1， and the BET specific surface area of PAF-106c increased from 135 m²/g to 280 m²/g. With the introduction of FDA， the BET specific surface area of PAF-106d—PAF-106g decreased with the increase of the ratio of FeCl₃ and FDA. In addition， the adsorption and separation properties of C2 hydrocarbons for PAF-106c were investigated at 273 and 298 K， and the selectivities for C₂H₂/C₂H₄ and C₂H₆/C₂H₄ were calculated by ideal adsorbed solution theory（IAST）.

Key words: Porous organic framework, Mechanical milling, Triphenylamine, Adsorption

CLC Number:

TrendMD:

CHEN Xiaolu, YUAN Zhenyan, ZHONG Yingchun, REN Hao. Preparation of Triphenylamine Based PAF-106s via Mechanical Ball Milling and C2 Hydrocarbons Adsorption Property[J]. Chem. J. Chinese Universities, 2022, 43(3): 20210771.

Figures/Tables 7

Scheme 1 Synthetic route for the PAF?106a—PAF?106c

Scheme 2 Synthetic route for the PAF?106d—PAF?106g

Fig.1 FTIR spectra of PAF?106a(a), PAF?106b(b), PAF?106c(c), triphenylamine(d)(A) and PAF?106d(a), PAF?106e(b), PAF?106f(c), PAF?106g(d), triphenylamine(e)(B)

Fig.2 13C NMR spectra of PAF?106c(a) and PAF?106g(b)Asterisk denotes spinning sideband.

Fig.3 N2 adsorption?desorption isotherms of PAF?106a(a), PAF?106b(b), PAF?106c(c)(A) and PAF?106d(a), PAF?106e(b), PAF?106f(c) and PAF?106g(d)(B)

Fig.4 Adsorption isotherms of C2H2, C2H4 and C2H6 for PAF?106c at 273 K(A), 298 K(B) and adsorption heats curves of C2H2, C2H4 and C2H6 for PAF?106c(C)

Fig.5 IAST selectivities for C2H2/C2H4 and C2H6/C2H4 for PAF?106c at 273 K(A) and 298 K(B)

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