Chem. J. Chinese Universities ›› 2015, Vol. 36 ›› Issue (9): 1759.doi: 10.7503/cjcu20150187
• Physical Chemistry • Previous Articles Next Articles
LI Zhaowan, QIAO Zhanping*(), CHEN Xin, DANG Yuanlin, YANG Qichao
Received:
2015-03-11
Online:
2015-09-10
Published:
2015-08-21
Contact:
QIAO Zhanping
E-mail:nyqiaozp@163.com
Supported by:
CLC Number:
TrendMD:
LI Zhaowan, QIAO Zhanping, CHEN Xin, DANG Yuanlin, YANG Qichao. Equilibria for the CsBr-TmBr3-H2O and CsBr-TmBr3-HBr(~13%)-H2O Systems at 298.15 K and Thermodynamic and Fluorescent Properties of New Solid-phase Compound[J]. Chem. J. Chinese Universities, 2015, 36(9): 1759.
No. | Saturated solution, wb(%) | Wet residue, w(%) | Solid phasec | No. | Saturated solution, wb(%) | Wet residue, w(%) | Solid phasec | ||||
---|---|---|---|---|---|---|---|---|---|---|---|
CsBr | TmBr3 | CsBr | TmBr3 | CsBr | TmBr3 | CsBr | TmBr3 | ||||
1 | 55.51 | 0 | A | 13 | 13.27 | 56.88 | 40.46 | 41.39 | A+B | ||
2 | 48.40 | 6.44 | 94.59 | 0.63 | A | 14 | 12.58 | 57.00 | 24.11 | 51.77 | B |
3 | 40.46 | 13.37 | 92.41 | 1.77 | A | 15 | 11.54 | 58.00 | 23.04 | 52.78 | B |
4 | 33.45 | 20.09 | 91.82 | 2.49 | A | 16 | 9.90 | 59.66 | 20.91 | 54.28 | B |
5 | 29.88 | 24.58 | 90.61 | 3.33 | A | 17 | 8.83 | 60.99 | 14.98 | 59.40 | B+C |
6 | 25.87 | 29.73 | 89.52 | 4.18 | A | 18 | 8.70 | 60.75 | 10.29 | 63.33 | B+C |
7 | 22.21 | 34.74 | 88.29 | 5.48 | A | 19 | 8.88 | 60.47 | 5.59 | 67.24 | B+C |
8 | 18.99 | 39.05 | 90.07 | 4.64 | A | 20 | 6.29 | 62.36 | 2.27 | 69.74 | C |
9 | 16.09 | 45.53 | 82.54 | 9.94 | A | 21 | 4.29 | 63.31 | 1.77 | 67.79 | C |
10 | 14.86 | 49.22 | 81.76 | 10.57 | A | 22 | 2.75 | 64.29 | 1.42 | 67.83 | C |
11 | 14.40 | 51.57 | 82.03 | 10.94 | A | 23 | 0 | 65.67 | C | ||
12 | 13.82 | 54.72 | 82.47 | 11.47 | A |
Table 1 Solubility data(mass fraction, %) for the ternary system CsBr-TmBr3-H2O at (298.15±0.1) K and (0.1±0.005) MPaa
No. | Saturated solution, wb(%) | Wet residue, w(%) | Solid phasec | No. | Saturated solution, wb(%) | Wet residue, w(%) | Solid phasec | ||||
---|---|---|---|---|---|---|---|---|---|---|---|
CsBr | TmBr3 | CsBr | TmBr3 | CsBr | TmBr3 | CsBr | TmBr3 | ||||
1 | 55.51 | 0 | A | 13 | 13.27 | 56.88 | 40.46 | 41.39 | A+B | ||
2 | 48.40 | 6.44 | 94.59 | 0.63 | A | 14 | 12.58 | 57.00 | 24.11 | 51.77 | B |
3 | 40.46 | 13.37 | 92.41 | 1.77 | A | 15 | 11.54 | 58.00 | 23.04 | 52.78 | B |
4 | 33.45 | 20.09 | 91.82 | 2.49 | A | 16 | 9.90 | 59.66 | 20.91 | 54.28 | B |
5 | 29.88 | 24.58 | 90.61 | 3.33 | A | 17 | 8.83 | 60.99 | 14.98 | 59.40 | B+C |
6 | 25.87 | 29.73 | 89.52 | 4.18 | A | 18 | 8.70 | 60.75 | 10.29 | 63.33 | B+C |
7 | 22.21 | 34.74 | 88.29 | 5.48 | A | 19 | 8.88 | 60.47 | 5.59 | 67.24 | B+C |
8 | 18.99 | 39.05 | 90.07 | 4.64 | A | 20 | 6.29 | 62.36 | 2.27 | 69.74 | C |
9 | 16.09 | 45.53 | 82.54 | 9.94 | A | 21 | 4.29 | 63.31 | 1.77 | 67.79 | C |
10 | 14.86 | 49.22 | 81.76 | 10.57 | A | 22 | 2.75 | 64.29 | 1.42 | 67.83 | C |
11 | 14.40 | 51.57 | 82.03 | 10.94 | A | 23 | 0 | 65.67 | C | ||
12 | 13.82 | 54.72 | 82.47 | 11.47 | A |
Fig.1 Phase diagram for the ternary system CsBr-TmBr3-H2O at 298.15 KE1 and E2 stand for double saturation point. B and C stand for Cs3Tm2Br9·16H2O and TmBr3·8H2O, respectively.
Fig.2 Phase diagram for the quaternary system CsBr-TmBr3-HBr(~13%)-H2O projected on CsBr-TmBr3-H2O at 298.15 KE1 and E2 stand for double saturation point. B and C stand for Cs3Tm2Br9·16H2O and TmBr3·8H2O, respectively.
No. | Composition of solution, w(%) | Composition of residue, w(%) | Solid phasec | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
In the tetrahedron | In the trigonal basal faceb | In the tetrahedron | In the trigonal basal face | ||||||||
HBr | CsBr | TmBr3 | CsBr | TmBr3 | HBr | CsBr | TmBr3 | CsBr | TmBr3 | ||
1 | 12.46 | 36.77 | 0.00 | 42.00 | 0.00 | A | |||||
2 | 13.81 | 30.76 | 5.02 | 35.69 | 5.83 | 1.83 | 91.28 | 0.69 | 92.98 | 0.71 | A |
3 | 13.06 | 24.84 | 11.93 | 28.58 | 13.73 | 1.84 | 91.93 | 1.35 | 93.66 | 1.37 | A |
4 | 13.88 | 18.90 | 22.08 | 21.94 | 25.64 | 1.96 | 89.45 | 3.02 | 91.24 | 3.08 | A |
5 | 13.45 | 15.88 | 29.02 | 18.34 | 33.53 | 1.60 | 90.15 | 3.23 | 91.61 | 3.28 | A |
6 | 13.57 | 15.17 | 34.69 | 17.55 | 40.13 | 2.33 | 86.34 | 5.59 | 88.40 | 5.72 | A |
7 | 13.89 | 14.64 | 36.42 | 17.00 | 42.30 | 2.55 | 85.03 | 6.61 | 87.25 | 6.78 | A |
8 | 13.76 | 14.77 | 37.42 | 17.13 | 43.39 | 2.56 | 83.54 | 6.53 | 85.73 | 6.70 | A |
9 | 13.24 | 15.40 | 39.09 | 17.75 | 45.05 | 6.51 | 36.32 | 42.22 | 38.85 | 45.16 | A+B |
10 | 13.05 | 13.11 | 40.82 | 15.08 | 46.95 | 6.63 | 28.25 | 43.11 | 30.26 | 46.18 | B |
11 | 13.45 | 11.07 | 42.86 | 12.79 | 49.52 | 6.11 | 28.27 | 43.92 | 30.11 | 46.77 | B |
12 | 12.40 | 8.82 | 46.33 | 10.07 | 52.89 | 5.66 | 26.84 | 45.62 | 28.45 | 48.36 | B |
13 | 12.72 | 8.25 | 46.23 | 9.45 | 52.97 | 4.26 | 16.33 | 55.57 | 17.06 | 58.04 | B+C |
14 | 12.70 | 8.66 | 46.25 | 9.93 | 52.98 | 3.77 | 2.53 | 65.86 | 2.63 | 68.44 | C |
15 | 12.52 | 4.59 | 48.61 | 5.25 | 55.57 | 3.08 | 1.53 | 67.96 | 1.58 | 70.12 | C |
16 | 12.33 | 1.87 | 50.22 | 2.13 | 57.28 | 2.80 | 1.00 | 68.79 | 1.03 | 70.77 | C |
17 | 12.28 | 0.00 | 51.46 | 0.00 | 58.66 | C |
Table 2 Solubility data(mass fraction, %) of the saturated solution of the quaternary system CsBr-TmBr3-HBr(13.09%)-H2O and central projection data on the trigonal basal face CsBr-TmBr3-H2O at (298.15±0.1) K and (0.1±0.005) MPaa
No. | Composition of solution, w(%) | Composition of residue, w(%) | Solid phasec | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
In the tetrahedron | In the trigonal basal faceb | In the tetrahedron | In the trigonal basal face | ||||||||
HBr | CsBr | TmBr3 | CsBr | TmBr3 | HBr | CsBr | TmBr3 | CsBr | TmBr3 | ||
1 | 12.46 | 36.77 | 0.00 | 42.00 | 0.00 | A | |||||
2 | 13.81 | 30.76 | 5.02 | 35.69 | 5.83 | 1.83 | 91.28 | 0.69 | 92.98 | 0.71 | A |
3 | 13.06 | 24.84 | 11.93 | 28.58 | 13.73 | 1.84 | 91.93 | 1.35 | 93.66 | 1.37 | A |
4 | 13.88 | 18.90 | 22.08 | 21.94 | 25.64 | 1.96 | 89.45 | 3.02 | 91.24 | 3.08 | A |
5 | 13.45 | 15.88 | 29.02 | 18.34 | 33.53 | 1.60 | 90.15 | 3.23 | 91.61 | 3.28 | A |
6 | 13.57 | 15.17 | 34.69 | 17.55 | 40.13 | 2.33 | 86.34 | 5.59 | 88.40 | 5.72 | A |
7 | 13.89 | 14.64 | 36.42 | 17.00 | 42.30 | 2.55 | 85.03 | 6.61 | 87.25 | 6.78 | A |
8 | 13.76 | 14.77 | 37.42 | 17.13 | 43.39 | 2.56 | 83.54 | 6.53 | 85.73 | 6.70 | A |
9 | 13.24 | 15.40 | 39.09 | 17.75 | 45.05 | 6.51 | 36.32 | 42.22 | 38.85 | 45.16 | A+B |
10 | 13.05 | 13.11 | 40.82 | 15.08 | 46.95 | 6.63 | 28.25 | 43.11 | 30.26 | 46.18 | B |
11 | 13.45 | 11.07 | 42.86 | 12.79 | 49.52 | 6.11 | 28.27 | 43.92 | 30.11 | 46.77 | B |
12 | 12.40 | 8.82 | 46.33 | 10.07 | 52.89 | 5.66 | 26.84 | 45.62 | 28.45 | 48.36 | B |
13 | 12.72 | 8.25 | 46.23 | 9.45 | 52.97 | 4.26 | 16.33 | 55.57 | 17.06 | 58.04 | B+C |
14 | 12.70 | 8.66 | 46.25 | 9.93 | 52.98 | 3.77 | 2.53 | 65.86 | 2.63 | 68.44 | C |
15 | 12.52 | 4.59 | 48.61 | 5.25 | 55.57 | 3.08 | 1.53 | 67.96 | 1.58 | 70.12 | C |
16 | 12.33 | 1.87 | 50.22 | 2.13 | 57.28 | 2.80 | 1.00 | 68.79 | 1.03 | 70.77 | C |
17 | 12.28 | 0.00 | 51.46 | 0.00 | 58.66 | C |
No. | m/mg | Qs/mJ | Δsol |
---|---|---|---|
1 | 64.80 | -416.9 | -11.22 |
2 | 65.72 | -449.7 | -11.93 |
3 | 65.27 | -445.5 | -11.90 |
4 | 67.88 | -470.1 | -12.07 |
5 | 63.79 | -404.3 | -11.05 |
Meanb | -(11.63±0.46) |
Table 3 Molar enthalpy of solution of Cs3Tm2Br9·16H2O in deionized water at (298.15±0.01) Ka
No. | m/mg | Qs/mJ | Δsol |
---|---|---|---|
1 | 64.80 | -416.9 | -11.22 |
2 | 65.72 | -449.7 | -11.93 |
3 | 65.27 | -445.5 | -11.90 |
4 | 67.88 | -470.1 | -12.07 |
5 | 63.79 | -404.3 | -11.05 |
Meanb | -(11.63±0.46) |
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