Chem. J. Chinese Universities ›› 2015, Vol. 36 ›› Issue (5): 1012.doi: 10.7503/cjcu20141022
• Polymer Chemistry • Previous Articles Next Articles
PENG Wei1, WANG Lijun1, QIAO Xiuying1,*(), SHAO Zhengzhong2, SUN Kang1
Received:
2014-11-18
Online:
2015-05-10
Published:
2015-04-15
Contact:
QIAO Xiuying
E-mail:xyqiao@sjtu.edu.cn
CLC Number:
TrendMD:
PENG Wei, WANG Lijun, QIAO Xiuying, SHAO Zhengzhong, SUN Kang. Emulsification Activity of Natural Silk Fibroin[J]. Chem. J. Chinese Universities, 2015, 36(5): 1012.
Fig.1 Illustration of the preparation process of the emulsions stabilized by silk fibroina. Silk fibroin water solution with different concentration(φSF); b. adding different oil with different volume fraction(ϕO) on the top; c. polydisperse emulsion; d. final stable emulsion with resolved water on the bottom.
Fig.2 Change of EAI with silk fibroin concentration for the emulsions stabilized by silk fibroin with ϕO=0.3 and different oil phasesa. Dodecane; b. butyl butyrate; c. hexanol.
Fig.3 Change of EAI with oil volume fraction for the emulsions stabilized by silk fibroin with φSF=5 mg/mL and different oil phasesa. Dodecane; b. butyl butyrate; c. hexanol.
Fig.4 Photos of the vessels containing the O/W emulsions stabilized by silk fibroin with ϕO=0.3 and different φSF initially in water and different oil phases for 7 d (A) Dodecane; (B) butyl butyrate; (C) hexanol. φSF/(mg·mL-1): a. 2.5; b. 5; c. 10.
Oil phase | φSF /(mg·mL-1) | ϕO | Stable emulsion fraction(%) | Droplet size/μm | Zeta-potential/mV |
---|---|---|---|---|---|
Dodecane | 2.5 | 0.3 | 47.2 | 27.5 | -28 |
5 | 0.3 | 52.8 | 35.4 | -30.7 | |
10 | 0.3 | 55.6 | 53.8 | -34.2 | |
5 | 0.2 | 38.9 | 32.0 | -32.8 | |
5 | 0.4 | 65.3 | 37.8 | -29.6 | |
Butyl butyrate | 2.5 | 0.3 | 60.5 | 30.3 | -19.5 |
5 | 0.3 | 78.4 | 26.3 | -21.4 | |
10 | 0.3 | 84.2 | 21.9 | -25.2 | |
5 | 0.2 | 63.2 | 25.0 | -20.4 | |
5 | 0.4 | 89.5 | 28.7 | -22.6 | |
Hexanol | 2.5 | 0.3 | 65.0 | 35.6 | -24.6 |
5 | 0.3 | 77.5 | 27.5 | -31.2 | |
10 | 0.3 | 77.5 | 22.5 | -30.9 | |
5 | 0.2 | 45.0 | 23.0 | -27.2 | |
5 | 0.4 | 95.0 | 45.5 | -27.6 |
Table 1 Stable emulsion fraction, droplet size and droplet surface charge of different emulsions stabilized by silk fibroin with different φSF initially in water, different ϕO and different oil phases
Oil phase | φSF /(mg·mL-1) | ϕO | Stable emulsion fraction(%) | Droplet size/μm | Zeta-potential/mV |
---|---|---|---|---|---|
Dodecane | 2.5 | 0.3 | 47.2 | 27.5 | -28 |
5 | 0.3 | 52.8 | 35.4 | -30.7 | |
10 | 0.3 | 55.6 | 53.8 | -34.2 | |
5 | 0.2 | 38.9 | 32.0 | -32.8 | |
5 | 0.4 | 65.3 | 37.8 | -29.6 | |
Butyl butyrate | 2.5 | 0.3 | 60.5 | 30.3 | -19.5 |
5 | 0.3 | 78.4 | 26.3 | -21.4 | |
10 | 0.3 | 84.2 | 21.9 | -25.2 | |
5 | 0.2 | 63.2 | 25.0 | -20.4 | |
5 | 0.4 | 89.5 | 28.7 | -22.6 | |
Hexanol | 2.5 | 0.3 | 65.0 | 35.6 | -24.6 |
5 | 0.3 | 77.5 | 27.5 | -31.2 | |
10 | 0.3 | 77.5 | 22.5 | -30.9 | |
5 | 0.2 | 45.0 | 23.0 | -27.2 | |
5 | 0.4 | 95.0 | 45.5 | -27.6 |
Fig.5 Microscope images for the oil/water emulsions stabilized by silk fibroin with the same φSF initially in water(φSF =5 mg/mL) but different ϕO and oil phases for 7 d(A) ϕO=0.2, dodecane; (B) ϕO=0.3, dodecane; (C) ϕO=0.4, dodecane; (D) ϕO=0.2, butyl butyrate; (E) ϕO=0.3, butyl butyrate; (F) ϕO=0.4, butyl butyrate; (G) ϕO=0.2, hexane; (H) ϕO=0.3, hexane; (I) ϕO=0.4, hexane.
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